Certain aromatic or heterocyclic mercapto-alkylene-cyclohexene dione intermediates

ABSTRACT

A novel cyclohexane compound represented by the general formula (I), ##STR1## wherein R 1  represents a hydrogen atom or a (C 1  -C 6 )alkyl or (C 1  -C 4 )alkoxymethyl group, R 2  represents a (C 1  -C 12 )-alkyl, (C 3  -C 6 )alkenyl, (C 3  -C 6 )alkynyl, (C 3  -C 6 )cycloalkylmethyl, halo(C 3  -C 6 )alkenyl, cyano(C 1  -C 4 )alkyl, (C 1  -C 4 )alkoxymethyl, (C 1  -C 4 )alkylthiomethyl or benzyl group, R 3  represents a hydrogen atom or a methyl group, R 4  represents a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, and when R 5  is a hydrogen atom, R 6  is a hydrogen atom or a (C 1  -C 4 )-alkoxycarbonyl group, and when R 5  is a methyl group, R 6  is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom, Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its meal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

This is a division of application Ser. No. 071,662, filed July 9, 1987, now U.S. Pat. No. 4,789,396.

The present invention relates to a novel cyclohexane compound represented by the general formula (I), ##STR2## wherein R¹ represents a hydrogen atom or a (C₁ -C₆)alkyl or (C₁ -C₄)alkoxymethyl group, R² represents a (C₁ -C₁₂)-alkyl, (C₃ -C₆)alkenyl, (C₃ -C₆)alkynyl, (C₃ -C₆)cycloalkylmethyl, halo(C₃ -C₆)alkenyl, cyano(C₁ -C₄)alkyl, (C₁ -C₄)alkoxymethyl, (C₁ -C₄)alkylthiomethyl or benzyl group, R³ represents a hydrogen atom or a methyl group, R⁴ represents a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methyl group, and when R⁵ is a hydrogen atom, R⁶ is a hydrogen atom or a (C_(1-C) ₄)alkoxycarbonyl group, and when R⁵ is a methyl group, R⁶ is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom (flourine, chlorine, bromine or iodine atom), Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its metal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

It is described in Japanese Patent Publication Kokai (Laid-open) Nos. 46749/1979 and 115349/1979 that cyclohexane derivatives can be used as an active ingredient for herbicides. These compounds, however, may not always be said to be satisfactory because of their poor herbicidal activity and poor selectivity between crops and weeds.

In view of the situation like this, the present inventors extensively studied to develop a compound having excellent herbicidal activity, and as a result, found a compound having excellent herbicidal activity at low dosage rates and showing no phytotoxicity to crops. The present inventors thus attained to the present invention.

The present compounds exhibit both excellent herbicidal activity and excellent selectivity between crops and weeds, as described below. The present compounds, in foliage treatment and soil treatment in plow field, have a herbicidal activity against various weeds in question, for example, broadleaf weeds such as common purslane (Portulaca oleracea), chickweed (Stellaria media), common lambsquarters (Chenopodium album), redroot pigweed (Amaranthus retroflexus), radish (Raphanus sativus), velvetleaf (Abutilon theophrasti), prickly sida (Sida spinosa), black nightshade (Solanum nigrum), persian speedwell (Veronica persica), common cocklebur (Xanthium strumarium), morningglories (Ipomoea spp.), etc.; grassy weeds such as Japanese millet (Echinochloa frumentacea), barnyardgrass (Echinochloa crus-galli), giant foxtail (Setaria faberi), green foxtail (Setaria viridis), large crabgrass (Digitaria sanguinalis), annual bluegrass (Poa annua), blackgrass (Alopecurus myosuroides), oat (Avena sativa), wild oat (Avena fatua), johnsongrass (Sorghum halepense), shattercane (Sorghum bicolor), downy brome (Bromus tectorum), cheat (Bromus sealinus), bermudagrass (Cynodon dactylon), goosegrass (Eleusine indica), quackgrass (Agropyron repens), fall panicum (Panicum dichotomiflorum), sedge weeds such as purple nutsedge (Cyperus rotundus) and yellow nutsedge (Cyperus esculentus), etc., and yet, their phytotoxicity to main crops such as corn, wheat, barley, rice, soybean, peanut, cotton, beet, sunflower, etc. is not such a one as to cause a problem.

Further, the present compounds, in treatment under flooded condition in paddy field, show a herbicidal activity against various weeds in question, for example grassy weeds such as barnyardgrass (Echinochloa oryzicola), etc., and broadleaf weeds such as common falsepimpernel (Lindernia procumbens), long stemmed waterwort (Elatine triandra), etc., and yet, their phytotoxicity to rice is not such a one as to cause a problem.

Of the present compounds represented by the general formula (I), those in which R¹ is a methyl group, R² is an ethyl or propyl group, preferably an ethyl group, R³ is a hydrogen atom or a methyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methyl group, R⁶ is a hydrogen atom, X is a group represented by the formula CH, Y is a hydrogen atom, Z is a trifluoromethyl, triflluoromethoxy or 1, 1, 2, 2-tetrafluoroethoxy group and n is an integer of 0, show particularly excellent selectivity between grassy crops such as corn, wheat, rice, etc. and grassy weeds such as barnyardgrass (Echinochloa crus-galli), green foxtail, giant foxtail, large crabgrass, oat, johnsongrass, barnyardgrass (Echinochloa oryzicola), etc., and they are particularly preferred as a herbicide used in corn and wheat fields.

Also, of the present compounds represented by the general formula (I), those in which R¹ is an ethyl or propyl group, R² is a (C₃ -C₆)alkenyl group or halo(C₃ -C₆) alkenyl group, preferably an allyl or 2-butenyl group, R³ is a hydrogen atom or a methyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methyl group, R⁶ is hydrogen atom, X is a group represented by the formula CH or a nitrogen atom, Y is a hydrogen atom, Z is a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, preferably a trifluoromethyl or trifluoromethoxy group, show particularly excellent selectivity between rice and various weeds in paddy field, so that they are preferred as a herbicide for paddy field.

Also, of the present compounds represented by the general formula (I), those in which R¹ is an ethyl or propyl group, R² is a (C₁ -C₆)alkyl, C₃ -C₆)alkenyl or halo(C₃ 14 C₆)alkenyl group, R³ is a hydrogen atom or a methyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methyl group, and when R⁵ is a hydrogen atom, R⁶ is a hydrogen atom or a (C₁ -C₄)-alkoxycarbonyl group and when R⁵ is a methyl group, R⁶ is a hydrogen atom, X is a group represented by the formula CH or a nitrogen atom, Y is a hydrogen atom, Z is a trifluoromethyl or trifluoromethoxy group and n is an integer of 0, exhibit particularly excellent selectivity between broadleaf crops such as soybean, cotton, beet, peanut, sunflower, etc. and various grassy weeds, so that they are preferred as a herbicide for broadleaf crops.

Further, of the present compounds represented by the general formula (I), those in which R¹ is a methyl group, R² is a (C₁ -C₆,)alkyl, (C₃ -C₆)alkenyl or halo (C₃ -C₆)alkenyl group, R³ is a hydrogen atom or a methyl group, R⁴ is a hydrogen atom or a methyl group, R⁵ is a hydrogen atom or a methyl group, R⁶ is a hydrogen atom, X is a group represented by the formula CH, Y is a hydrogen atom, Z is a trifluoromethyl group and n is an integer of 0, have particularly a broad herbicidal spectrum, so that they are preferred as a herbicide used in orchards, forests, non-crop lands, etc.

Preferred compounds are 2-(1-propoxyaminoethylidene)-or 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl] cyclohexane-1,3-dione, 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethoxyphenylthio)ethyl] cyclohexane-1,3-dione, 2-(1-allyloxyaminobutylidene)- or 2-[1-(2-butenyl)oxyaminobutylidene]5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl] cyclohexane-1,3-dione and 2-(1-ehoxyaminopropylidene)-or 2-(1-allyloxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

Next, a method for producing the present compounds will be explained in detail. The present compounds can be produced by reacting acylcyclohexane represented by the general formula (II), ##STR3## wherein R¹,R³, R⁴, R⁵, R⁶, X, Y, Z and n are as defined above, with hydroxylamine represented by the general formula (III),

    NH.sub.2 OR.sup.2                                          (III)

wherein R² is as defined above, or its inorganic acid salt.

This reaction is generally carried out with or without a solvent, and as need arises, in the presence of a base, if necessary. The reaction temperature is in a range of from 0° to 100° C., and the reaction time is in a range of from 0.5 to 24 hours. The amount of the reagents used for reaction is from 1 to 2 equivalents for the amine (III) or its inorganic acid salt, and from 1 to 2 equivalents for the dehydrohalogenating agent based on 1 equivalent of acylcyclohexane (II).

The inorganic acid salt of the amine (III) includes hydrochloride, hydrobromide, sulfate, etc.

The solvent includes aliphatic hydrocarbons (e.g. hexane, heptane, ligroin, petroleum ether), aromatic hydrocarbons (e.g. benzene, toluene, xylene), halogenated hydrocarbons (e.g. chloroform, carbon tetrachloride, dichloroethane, chlorobenzene, dichlorobenzene), ethers (e.g. diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, diethylene glycol dimethyl ether), alcohols (e.g. methanol, ethanol, isopropanol, tert-butanol, octanol, cyclohexanol, methyl cellosolve, diethylene glycol, glycerin), esters (e.g. ethyl formate, ethyl acetate, butyl acetate, diethyl carbonate), nitro compounds (e.g. nitroethane, nitrobenzene), nitriles (e.g. acetonitrile, isobutyronitrile), tertiary amines (e.g. pyridine, triethylamine, N,N-diethylaniline, tributylamine, N-methylmorpholine), acid amides (e.g. formamide, N-N-dimethylformamide, acetamide), sulfur compounds (e.g. dimethyl sulfoxide, sulfolane), water and mixtures thereof.

The base includes organic bases (e.g. pyridine, triethylamine, N,N-diethylaniline), inorganic bases (e.g. sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydride), alkali metal alkoxides (e.g. sodium methoxide, sodium ethoxide), etc.

After completion of the reaction, the reaction solution is poured into water, made neutral to acidic, subjected to the usual after-treatment such as extraction with organic solvents, concentration, etc., and if necessary, purified by chromatography, distillation, recrystallization, etc.

The present compounds represented by the general formula (I) are considered to have the following tautomeric structures: ##STR4## wherein W represents ##STR5##

Similarly, acylcyclohexane represented by the general formula (II) are also considered to have the following tautomeric structures: ##STR6## wherein W represents ##STR7##

Next, examples of the present compound produced by the method of the present invention will be shown in Table 1.

                                      TABLE 1                                      __________________________________________________________________________     Cyclohexanes of the general formula:                                            ##STR8##                                                                      X  Y Z      R.sup.1 R.sup.2    R.sup.3                                                                           R.sup.4                                                                           R.sup.5                                                                           R.sup.6                                                                              n                                __________________________________________________________________________     CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR9##  "  "  "  "     "                                "  " "      "                                                                                       ##STR10## "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2CH.sub.2                                                                          H  H  H  H     0                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CN                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.3                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CCCH.sub.3                                                                       "  "  "  "     "                                "  " "      "       CH.sub.3   "  "  CH.sub.3                                                                          "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CH.sub.3                                                                         H  H  CH.sub.3                                                                          H     0                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2 ).sub.11 CH.sub.3                                                               "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR11## "  "  "  "     "                                "  " "      "                                                                                       ##STR12## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CH.sub.2 CHCH.sub.2                                                              H  H  CH.sub.3                                                                          H     0                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   "  "  H  "     1                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                                ##STR13## H  H  H  H     1                                "  " "      "                                                                  "  " "      "                                                                                       ##STR14## "  "  "  "     "                                "  " "      "       CH.sub.2 CH CH.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  H  H  H     2                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR15## "  "  "  "     "                                "  " "      "                                                                                       ##STR16## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     2                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   "  CH.sub.3                                                                          "  "     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                                ##STR17## H  CH.sub.3                                                                          H  H     0                                "  " "      "                                                                                       ##STR18## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2CH "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   CH.sub.3                                                                          H  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CH.sub.3                                                                         CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR19## "  "  "  "     "                                "  " "      "                                                                                       ##STR20## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CH.sub.2 CHCH.sub.2                                                              CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      C.sub.2 H.sub.5                                                                        CH.sub.3   H  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                         ##STR21## H  H  H  H     0                                "  " "      "                                                                                       ##STR22## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "                                                                                       ##STR23## "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CCCH.sub.3                                                                       H  H  H  H     0                                "  " "      "       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                                                      "  "  "  "     "                                "  " "      "       CH.sub.3   "  "  "  "     1                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR24## "  "  "  "     "                                "  " "      "                                                                                       ##STR25## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCHCH.sub.3                                                                     H  H  H  H     1                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH(CH.sub.3).sub. 2                                                                       H  H  H  H     2                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR26## "  "  "  "     "                                "  " "      "                                                                                       ##STR27## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 C.sub.6 H.sub.5                                                                  H  H  H  H     2                                "  " "      "       CH.sub.3   "  "  CH.sub.3                                                                          "     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR28## "  "  "  "     "                                "  " "      "                                                                                       ##STR29## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCHCl                                                                           H  H  CH.sub.3                                                                          H     0                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   "  CH.sub.3                                                                          H  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                CH H C.sub.2 H.sub.5                                                                       CH.sub.2 CH(CH.sub.3).sub.2                                                            H          CH.sub.3                                                                          H  H  0                                      "  " "      "                                                                                       ##STR30## "  "  "  "     "                                "  " "      "                                                                                       ##STR31## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.3   CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR32## "  "  "  "     "                                "  " "      "                                                                                       ##STR33## "  "  "  "     "                                "  " "      "       CH.sub.2CH.sub.2                                                                          "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub. 2                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR34## H  H  H  H     0                                "  " "      "                                                                                       ##STR35## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR36## "  "  "  "     "                                "  " "      "                                                                                       ##STR37## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      CH.sub.3                                                                          H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.3 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   H  CH.sub.3                                                                          "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR38## H  CH.sub.3                                                                          H  H     0                                "  " "      "                                                                                       ##STR39## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH(CH.sub.3).sub.2                                                                     CH.sub.3   H  CH.sub.3                                                                          "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR40## H  CH.sub.3                                                                          H  H     0                                "  " "      "                                                                                       ##STR41## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH(CH.sub.3).sub.2                                                                     CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH(CH.sub.3).sub.2                                                            CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub. 2 CH(CH.sub.3).sub.2                                                              "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH(CH.sub.3).sub.2                                                             ##STR42## H  H  H  H     0                                "  " "      "                                                                                       ##STR43## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 C CH                                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              H       CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR44## "  "  "  "     "                                "  " "      "                                                                                       ##STR45## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              H       CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 OCH.sub.3                                                                     CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 OCH.sub.3                                                                      ##STR46## H  H  H  H     0                                "  " "      "                                                                                       ##STR47## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.3                                                                               CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub. 2 CH(CH.sub.3).sub.2                                                              "  "  "  "     "                                "  " "      "                                                                                       ##STR48## "  "  "  "     "                                "  " "      "                                                                                       ##STR49## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 C CH                                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      C.sub.2 H.sub.5                                                                        CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H OCF.sub.3                                                                             C.sub.2 H.sub.5                                                                         ##STR50## H  H  H  H     0                                "  " "      "                                                                                       ##STR51## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR52## "  "  "  "     "                                "  " "      "                                                                                       ##STR53## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                               CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3 ).sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                                ##STR54## H  H  H  H     0                                "  " "      "                                                                                       ##STR55## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  C.sub.2 H.sub.5                                                                        CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2 ).sub.3 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR56## "  "  "  "     "                                "  " "      "                                                                                       ##STR57## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub. 3                                                                    "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                           

    __________________________________________________________________________      CH                                                                               H OCF.sub.2 CF.sub.2 H                                                                  C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub. 3).sub.2                                                              "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR58## H  H  H  H     0                                "  " "      "                                                                                       ##STR59## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 C CH                                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  CH                                                                               CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2 ).sub.4 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR60## "  "  "  "     "                                "  " "      "                                                                                       ##STR61## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  CH                                                                               CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  H "      C.sub.2 H.sub.5                                                                        CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                         ##STR62## H  H  H  H     0                                "  " "      "                                                                                       ##STR63## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR64## "  "  "  "     "                                "  " "      "                                                                                       ##STR65## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  Cl                                                                               "      CH.sub.3                                                                               CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                                ##STR66## H  H  H  H     0                                "  " "      "                                                                                       ##STR67## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR68## "  "  "  "     "                                "  " "      "                                                                                       ##STR69## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR70## H  H  H  H     0                                "  " "      "                                                                                       ##STR71## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                H  H CF.sub.3                                                                              CH.sub.2 OCH.sub.3                                                                     CH.sub.3   H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR72## "  "  "  "     "                                "  " "      "                                                                                       ##STR73## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  H CF.sub.3                                                                              CH.sub.2 OCH.sub.3                                                                     CH.sub.2 CHCCl.sub.2                                                                      H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      H       CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  H CF.sub.3                                                                              H                                                                                       ##STR74## H  H  H  H     0                                "  " "      "                                                                                       ##STR75## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR76## "  "  "  "     "                                "  " "      "                                                                                       ##STR77## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub. 2 CH.sub.2 CHCH.sub.2                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                                ##STR78## H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR79## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  H  H  COOCH.sub.3                                                                          2                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR80## "  "  "  "     "                                "  " "      "                                                                                       ##STR81## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          2                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                               "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   CH.sub.3                                                                          "  "  "     0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                                ##STR82## CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR83## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR84## "  "  "  "     "                                "  " "      "                                                                                       ##STR85## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  CH.sub.3                                                                          COOCH.sub.3                                                                       0                                      "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      C.sub.2 H.sub.5                                                                        CH.sub.3   "  H  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                         ##STR86## H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR87## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub. 2 CN                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.3   H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub. 2).sub.11 CH.sub.3                                                               "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR88## "  "  "  "     "                                "  " "      "                                                                                       ##STR89## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   CH.sub.3                                                                          "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                         ##STR90## CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR91## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR92## "  "  "  "     "                                "  " "      "                                                                                       ##STR93## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 C CH                                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      "       CH.sub.3   CH.sub.3                                                                          "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub. 2).sub.4 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR94## CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR95## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR96## "  "  "  "     "                                "  " "      "                                                                                       ##STR97## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH(CH.sub.3).sub.2                                                                     CH.sub.3   "  H  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H CF.sub.3                                                                              CH(CH.sub.3).sub.2                                                                      ##STR98## H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR99## "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H CF.sub.3                                                                              H       CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR100##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR101##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H CF.sub.3                                                                              H       CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " OCF.sub.3                                                                             CH.sub. 3                                                                              CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.3                                                                                ##STR102##                                                                               H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR103##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.3                                                                             C.sub.2 H.sub.5                                                                        CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR104##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR105##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                           

    __________________________________________________________________________      CH                                                                               H OCF.sub.3                                                                             C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H OCF.sub.3                                                                             CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR106##                                                                               H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR107##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 C CH                                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                               CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub. 4 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR108##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR109##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                               CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      C.sub.2 H.sub.5                                                                        CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  C.sub.2 H.sub.5                                                                         ##STR110##                                                                               H  H  H  COOCH.sub.3                                                                          0                                "  " "      "                                                                                       ##STR111##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR112##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR113##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOCH.sub.3                                                                          0                                "  " "      "       CH.sub.2 CH.sub.2 CH CH.sub.2                                                             "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  " CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3   "  "  "  COOC.sub.2 H.sub.5                                                                   "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  H CF.sub.3                                                                              CH.sub.3                                                                                ##STR114##                                                                               H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "                                                                                       ##STR115##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.3   H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR116##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR117##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  H CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  H CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR118##                                                                               H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "                                                                                       ##STR119##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  H CF.sub.3                                                                              H       CH.sub.3   H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR120##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR121##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  H CF.sub.3                                                                              H       CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  Cl                                                                               "      CH.sub.3                                                                               CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                                ##STR122##                                                                               H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "                                                                                       ##STR123##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.3   H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR124##                                                                               "  "  "  "     "                                "  " "      "                                                                                       ##STR125##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCCl.sub.2                                                                      H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.3   "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.3                                                                         "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.3 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.4 CH.sub.3                                                                 "  "  "  "     "                                "  " "      "       (CH.sub.2).sub.11 CH.sub.3                                                                "  "  "  "     "                                "  " "      "       CH(CH.sub.3).sub.2                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                               "  "  "  "     "                                N  Cl                                                                               CF.sub.3                                                                              CH.sub.2 CH.sub.2 CH.sub.3                                                              ##STR126##                                                                               H  H  H  COOC.sub.2 H.sub.5                                                                   0                                "  " "      "                                                                                       ##STR127##                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCH.sub.3                                                                     "  "  "  "     "                                "  " "      "       CH.sub.2 CHCHCl                                                                           "  "  "  "     "                                "  " "      "       CH.sub.2 CHCCl.sub.2                                                                      "  "  "  "     "                                "  " "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CCH                                                                              "  "  "  "     "                                "  " "      "       CH.sub.2 CN                                                                               "  "  "  "     "                                "  " "      "       CH.sub.2 OCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 SCH.sub.3                                                                        "  "  "  "     "                                "  " "      "       CH.sub.2 C.sub.6 H.sub.5                                                                  "  "  "  "     "                                CH F CF.sub.3                                                                              CH.sub.3                                                                               C.sub.2 H.sub.5                                                                           H  H  H  H     0                                "  " "      "       CH.sub.2 CH.sub.2 CH.sub.3                                                                "  "  "  "     "                                "  " "      C.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                           "  "  "  "     "                                "  " "      CH.sub.2 CH.sub.2 CH.sub.3                                                             "          "  "  "  "     "                                "  " "      "       CH.sub.2 CHCH.sub.2                                                                       "  "  "  "     "                                "  Br                                                                               "      CH.sub.3                                                                               C.sub.2 H.sub.5                                                                           "  "  "  "     "                                __________________________________________________________________________

The compound represented by the general formula (I) can form a salt such as metal, ammonium and organic ammonium salt, which have a herbicidal activity.

The salt can be prepared by reacting a compound represented by the general formula (I) with potassium hydroxide or sodium hydroxide in solvent such as water, acetone and alcohol to form a potassium or sodium salt and following by reacting the potassium or sodium salt with another salt such as metal chloride, hydroxide, sulfate and nitrate.

The organic ammonium salt can be prepared by reacting a compound represented by the general formula (I) with organic ammonium hydroxide in solvent such as water, acetone and alcohol.

The organic ammonium salt includes a tetraalkylammonium salt, benzyltrialkylammonium salt, etc.

PRODUCTION EXAMPLE 1

0.6 Gram of 2-butyryl-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dione was dissolved in a mixed solvent of 10 ml of ethanol and 1 ml of water, and 0.2 g of ethoxyamine hydrochloride and 0.07 g of sodium hydroxide were added to the resulting solution which was then stirred at room temperature for 2.5 hours. The reaction solution was poured into water, weakly acidified and extracted with ethyl acetate. After removing ethyl acetate, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.45 g of 2-(1-ethoxyaminobutylidene)-5-[2-(5-trifluoromethyl-2-pyridylthio)-ethyl]cyclohexane-1,3-dione.

n_(D) ²¹.5 :1.5439.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.58 (1H, s), 8.65 (1H, s), 7.65 (1H, dd), 7.23 (1H, d), 4.11 (2H, q), 3.25 (2H, t), 3.1-1.5 (11H, m), 1.29 (3H, t), 0.84 (3H, t).

PRODUCTION EXAMPLE 2

0.19 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 5 ml of ethanol, and 0.07 g of allyloxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.13 g of 2-(1-allyloxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ¹⁹.5 :1.5624.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.63 (1H, s), 7.46 (4H, ABq), 6.35-5.71 (1H, m), 5.45 (2H, bd), 5.23 (1H, m), 4.54 (2H, d), 3.01 (2H, t), 3.0-1.5 (9H, m), 1.14 (3H, t).

PRODUCTION EXAMPLE 3

2.1 Grams of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.71 g of ethoxyamine hydrochloride and 0.68 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by column chromatography on silica gel (eluent, ethyl acetate:hexane=1:5) to obtain 1.2 g of 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione as white crystals.

m.p., 92°-93° C.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 14.63 (1H, bs), 7.41 (4H, ABq), 4.09 (2H, q), 3.02 (2H, t), 2.36 (3H, s), 2.8-1.5 (7H, m), 1.31 (3H, t).

PRODUCTION EXAMPLE 4

0.19 Gram of 2-acetyl-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.07 g of ethoxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.12 g of 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁶ :1.5329.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 7.22 (4H, ABq), 4.11 (2H, q), 3.05 (2H, t), 2.35 (3H, s), 2.8-1.5 (7H, m), 1.30 (3H, t), 15-14 (1H, br).

PRODUCTION EXAMPLE 5

0.21 Gram of 2-propionyl-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.06 g of ethoxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by thin layer chromatography (developing solvent, hexane:ethyl acetate=5:1) to obtain 0.07 g of 2-(1-ethoxyaminopropylidene)-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁴ :1.5119.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 7.28 (4H, ABq), 5.92 (1H, tt, J=54 Hz, 3 Hz), 4.13 (2H, q), 3.1-1.5 (9H, m), 1.31 (3H, t), 1.13 (3H, t), 15-14 (1H, br).

PRODUCTION EXAMPLE 6

0.27 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)propyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethyl acetate, and 0.08 g of ethoxyamine hydrochloride and 0.1 g of N,N-diethylaniline were added to the resulting solution which was then refluxed for 5 hours. The reaction solution was cooled to room temperature, poured into water, weakly acidified and extracted with ethyl acetate. The ethyl acetate layer was washed with dilute hydrochloric acid and water subsequently and dried over anhydrous magnsium sulfate. After removing ethyl acetate, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.13 g of 2-(1-ethoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)propyl]-cyclohexane-1,3-dione.

n_(D) ²⁴ :1.5293.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br), 7.45 (4H, brs), 4.10 (2H, q), 3.32 (1H, m), 2.7-1.5 (9H, m), 1.35 (3H, d), 1.31 (3H, t), 1.14 (3H, t).

PRODUCTION EXAMPLE 7

0.4 Gram of 2-acetyl-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione and 0.1 g of ethoxyamine hydrochloride were dissolved in 10 ml of methanol and 0.15 g of potassium carbonate was added to the resulting solution which was then refluxed for 3 hours. The reaction solution was poured into water and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.3 g of 2-(1-ethoxyaminoethylidene)-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁵.5 :1.5145.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br), 7.39 (4H, ABq), 4.11 (2H, q), 3.0-1.5 (6H, m), 2.93 (2H, t), 2.34 (3H, s), 1.30 (3H, t), 1.12 (3H, d).

PRODUCTION EXAMPLE 8

To the suspension of 0.3 g of sodium hydride (60% oil dispersion) in 10 ml of dimethylformamide, 0.09 g of 2-butenyloxyamine hydrochloride was added under cooling with ice-water bath and then stirred. After 30 minutes, 0.21 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was added to the resulting solution which was then stirred for 7 hours under cooling with ice-water bath. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with ether. After removing ether, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.22 g of 2-[1-(2-butenyloxyamino)ethylidene]-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

m.p. 72°-73° C.

Nuclear magnetic resonance (CDCl₃): δ (ppm) 15-14 (1H, br), 7.35 (4H, ABq), 5.55 (2H, m), 4.35 (2H, d), 2.91 (2H, t), 2.5-1.5 (7H, m), 2.34 (3H, s), 1.7 (3H, brd).

PRODUCTION EXAMPLE 9

0.2 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of chloroform and 0.07 g of propoxyamine hydrochloride and 0.5 ml of pyridine were added to the resulting solution which was then stirred at 50°-60° C. for 5 hours. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.11 g of 2-(1-propoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

n_(D) ²⁴ :1.5376.

Nuclear magnetic resonance spectrum (CDCl₃): δ (ppm) 15-14 (1H, br), 7.43 (4H, ABq), 4.00 (2H, t), 3.2-1.5 (13H, m), 1.15 (3H, t), 0.99 (3H, t).

Some of the present compounds produced by the methods described above will be shown in Table 2.

                                      TABLE 2                                      __________________________________________________________________________     General formula:                                                                ##STR128##                                                                    Compound                                               Physical                No.   X  Y  Z      R.sup.1 R.sup.2  R.sup.3                                                                            R.sup.4                                                                           R.sup.5                                                                           R.sup.6                                                                              n  properties              __________________________________________________________________________     1     CH H  CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3 H   H  H  H     0  mp 76-77°                                                               C.                      2     "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  mp 92-93°                                                               C.                      3     "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  mp 91-92°                                                               C.                      4     "  "  "      "       n-C.sub.4 H.sub.9                                                                       "   "  "  "     "  n.sub.D.sup.24                                                                 1.5092                  5     "  "  "      "       n-C.sub.5 H.sub.11                                                                      "   "  "  "     "  n.sub.D.sup.24                                                                 1.5265                  6     "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "   "  "  "     "  n.sub.D.sup.23                                                                 1.5322                  7     "  "  "      "       CH(CH.sub.3).sub.2                                                                      "   "  "  "     "  mp 94-95°                                                               C.                      8     "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "  "  "     "  mp 76-77°                                                               C.                      9     "  "  "      "                                                                                       ##STR129##                                                                             "   "  "  "     "  mp 86-87°                                                               C.                      10    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5165                  11    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  mp 72-73°                                                               C.                      12    CH H  CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.2 CHCHCl                                                                         H   H  H  H     0  n.sub.D.sup.23.5                                                               1.5572                  13    "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "   "  "  "     "  n.sub.D.sup.24.5                                                               1.5519                  14    "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "   "  "  "     "  n.sub.D.sup.22.5                                                               1.5450                  15    "  "  "      "       CH.sub.2 CCH                                                                            "   "  "  "     "  N.sub.D.sup.24                                                                 1.5516                  16    "  "  "      "       CH.sub.2 CN                                                                             "   "  "  "     "  n.sub.D.sup.24                                                                 1.5276                  17    "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "   "  "  "     "  mp 86.5-                                                                       87.5° C.         18    "  "  "      "       CH.sub.2 SCH.sub.3                                                                      "   "  "  "     "  mp 80-81°                                                               C.                      19    "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "   "  "  "     "  mp 72-73°0                                                              C.                      20    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  CH.sub.3                                                                          "     "  n.sub.D.sup.23                                                                 1.5181                  21    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.23                                                                 1.5276                  22    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  H  "     1  mp 103-104°                                                             C.                      23    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.22.5                                                               1.5384                  24    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     2  mp 120-121°                                                             C.                      25    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  mp 117-118°                                                             C.                      26    CH H  CF.sub.3                                                                              CH.sub.3                                                                               C.sub.2 H.sub.5                                                                         CH.sub.3                                                                           H  H  H     0  n.sub.D.sup.24                                                                 1.5347                  27    "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.24                                                                 1.5336                  28    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5372                  29    "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5461                  30    "  "  "      "       C.sub.2 H.sub.5                                                                         H   CH.sub.3                                                                          "  "     "  n.sub.D.sup.25.5                                                               1.5371                  31    "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.25.5                                                               1.5145                  32    "  "  "      C.sub.2 H.sub.5                                                                        CH.sub.3 "   H  "  "     "  n.sub.D.sup.24                                                                 1.5426                  33    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5333                  34    "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.24                                                                 1.5376                  35    "  "  "      "       n-C.sub.4 H.sub.9                                                                       "   "  "  "     "  n.sub.D.sup.24                                                                 1.5058                  36    "  "  "      "       n-C.sub.5 H.sub.11                                                                      "   "  "  "     "  n.sub.D.sup.24                                                                 1.5251                  37    "  "  "      "       (CH.sub.2).sub.11 CH.sub.3                                                              "   "  "  "     "  n.sub.D.sup.23                                                                 1.5325                  38    "  "  "      "       CH(CH.sub.3).sub.2                                                                      "   "  "  "     "  n.sub.D.sup. 23                                                                1.5328                  39    "  "  "      "       CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "  "  "     "  n.sub.D.sup.23                                                                 1.5465                  40    "  "  "      "                                                                                       ##STR130##                                                                             "   "  "  "     "  n.sub.D.sup.24                                                                 1.5456                  41    CH H  CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCH.sub.2                                                                     H   H  H  H     0  n.sub.D.sup.19.5                                                               1.5399                  42    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.21.5                                                               1.5344                  43    "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5416                  44    "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "   "  "  "     "  n.sub.D.sup.24                                                                 1.5549                  45    "  "  "      "       CH.sub.2 CH.sub.2 CHCH.sub.2                                                            "   "  "  "     "  n.sub.D.sup.23                                                                 1.5365                  46    "  "  "      "       CH.sub.2 CCH                                                                            "   "  "  "     "  n.sub.D.sup.24                                                                 1.5499                  47    "  "  "      "       CH.sub.2 CN                                                                             "   "  "  "     "  n.sub.D.sup.24                                                                 1.5276                  48    "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "   "  "  "     "  n.sub.D.sup.21.5                                                               1.5352                  49    "  "  "      "       CH.sub.2 SCH                                                                            "   "  "  "     "  n.sub.D.sup.24                                                                 1.5616                  50    "  "  "      "       CH.sub.2 C.sub.6 H.sub.5                                                                "   "  "  "     "  n.sub.D.sup.24                                                                 1.5697                  51    "  "  "      "       C.sub.2 H.sub.5                                                                         CH.sub.3                                                                           "  "  "     "  n.sub.D.sup.24                                                                 1.5293                  52    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5249                  53    "  "  "      n-C.sub.3 H.sub.7                                                                      CH.sub.3 H   "  "  "     "  n.sub.D.sup.24                                                                 1.5391                  54    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5345                  55    "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.24                                                                 1.5320                  56    CH H  CF.sub.3                                                                              n-C.sub.3 H.sub.7                                                                      CH.sub.2 CHCH.sub.2                                                                     H   H  H  H     0  n.sub.D.sup.19.5                                                               1.5402                  57    "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     0  n.sub.D.sup.25.5                                                               1.5152                  58    "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "   "  "  "     "  n.sub.D.sup.24                                                                 1.5605                  59    "  "  "      "       C.sub.2 H.sub.5                                                                         CH.sub.3                                                                           "  "  "     "  n.sub.D.sup.24                                                                 1.5229                  60    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5298                  61    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.24                                                                 1.5263                  62    "  "  "      CH(CH.sub.3).sub.2                                                                     C.sub.2 H.sub.5                                                                         H   "  "  "     "  n.sub.D.sup.24                                                                 1.52.78                 63    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.24                                                                 1.5282                  64    "  "  "      CH.sub.2 CH(CH.sub.3).sub.2                                                            CH.sub.3 "   "  "  "     "  n.sub.D.sup.24                                                                 1.5295                  65    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5351                  66    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.24                                                                 1.5306                  67    "  "  "      CH.sub.2 OCH.sub.3                                                                     C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.22                                                                 1.5286                  68    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.22                                                                 1.5461                  69    "  "  OCF.sub.3                                                                             CH.sub.3                                                                               CH.sub.3 "   "  "  "     "  n.sub.D.sup.26                                                                 1.5376                  70    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.26                                                                 1.5329                  71    CH H  OCF.sub.3                                                                             CH.sub.3                                                                               n-C.sub.3 H.sub.7                                                                       H   H  H  H     0  mp 57-58°                                                               C.                      72    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.26                                                                 1.5406                  73    "  "  "      C.sub.2 H.sub.5                                                                        CH.sub.3 "   "  "  "     "  n.sub.D.sup.27.5                                                               1.5337                  74    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.27.5                                                               1.5226                  75    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.27.5                                                               1.5308                  76    "  "  "      n-C.sub.3 H.sub.7                                                                      CH.sub.3 "   "  "  "     "  n.sub.D.sup.26                                                                 1.5059                  77    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.26                                                                 1.5196                  78    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.26                                                                 1.5283                  79    "  "  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                               C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24.5                                                               1.5244                  80    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24.5                                                               1.5213                  81    "  "  "      C.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5119                  82    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5286                  83    "  "  "      n-C.sub.3 H.sub.7                                                                      C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.24                                                                 1.5185                  84    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.24                                                                 1.5248                  85    N  "  CF.sub.3                                                                              CH.sub.3                                                                               CH.sub.3 "   "  "  "     "  n.sub.D.sup.22                                                                 1.5402                  86    N  H  CF.sub.3                                                                              CH.sub.3                                                                               C.sub.2 H.sub.5                                                                         H   H  H  H     0  n.sub.D.sup.22                                                                 1.5518                  87    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.21                                                                 1.5405                  88    "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.22                                                                 1.5552                  89    "  "  "      C.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.26                                                                 1.5374                  90    "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.23                                                                 1.5302                  91    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.20                                                                 1.5298                  92    "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.20                                                                 1.5271                  93    "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.20                                                                 1.5386                  94    "  "  "      "       CH.sub.2 CHCCl.sub.2                                                                    "   "  "  "     "  n.sub.D.sup.23                                                                 1.5175                  95    "  "  "      "       CH.sub.2 CCH                                                                            "   "  "  "     "  n.sub.D.sup.21                                                                 1.5378                  96    "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "   "  "  "     "  n.sub.D.sup.21                                                                 1.5172                  97    "  "  "      n-C.sub.3 H.sub.7                                                                      CH.sub.3 "   "  "  "     "  n.sub.D.sup.21                                                                 1.5372                  98    "  "  "      "       C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.21.5                                                               1.5239                  99    "  "  "      "       CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.21.5                                                               1.5331                  100   "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  n.sub.D.sup.21                                                                 1.5361                  101   N  H  CF.sub.3                                                                              n-C.sub.3 H.sub.7                                                                      CH.sub.2 CHCHCl                                                                         H   H  H  H     0  n.sub.D.sup.20                                                                 1.5432                  102   "  "  "      "       CH.sub.2 CCH                                                                            "   "  "  "     "  n.sub.D.sup.20                                                                 1.5517                  103   "  "  "      "       CH.sub.2 CN                                                                             "   "  "  "     "  n.sub.D.sup.20                                                                 1.5192                  104   "  "  "      "       CH.sub.2 OCH.sub.3                                                                      "   "  "  "     "  n.sub.D.sup.21                                                                 1.5212                  105   "  Cl "      C.sub.2 H.sub.5                                                                        CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  mp 64-65°                                                               C.                      106   "  "  "      "       CH.sub.2 CHCHCH.sub.3                                                                   "   "  "  "     "  mp 58-59°                                                               C.                      107   "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.20                                                                 1.5472                  108   "  Cl "      n-C.sub.3 H.sub.7                                                                      CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.19                                                                 1.5287                  109   "  H  "      CH.sub.2 OCH.sub.3                                                                     CH.sub.2 CHCH.sub.2                                                                     "   "  "  "     "  n.sub.D.sup.20                                                                 1.5397                  110   "  "  "      "       CH.sub.2 CHCHCl                                                                         "   "  "  "     "  n.sub.D.sup.26                                                                 1.5269                  111*  CH "  "      CH.sub.3                                                                               C.sub.2 H.sub.5                                                                         "   "  "  "     "  mp 175-178°                                                             C.                                                                             (dec.)                  112*  "  "  "      "       "        "   "  "  "     "  mp 144-146°                                                             C.                                                                             (dec.)                  113*  "  "  "      "       "        "   "  "  "     "  mp 182-185°                                                             C.                                                                             (dec.)                  114*  CH H  CF.sub.3                                                                              CH.sub.3                                                                               C.sub.2 H.sub.5                                                                         H   H  H  H     0  mp 72-73°                                                               C.                      115*  "  "  "      "       "        "   "  "  "     "  mp 232-235°                                                             C.                                                                             (dec.)                  116*  "  "  "      "       "        "   "  "  "     "  mp 58-61°                                                               C.                      117   "  "  "      "       "        "   "  "  COOCH.sub.3                                                                          "  n.sub.D.sup.23.5                                                               1.5376                  118   "  "  "      C.sub.2 H.sub.5                                                                        "        "   "  "  "     "  n.sub.D.sup.24                                                                 1.5339                  119   "  "  "      n-C.sub.3 H.sub.7                                                                      "        "   "  "  "     "  n.sub.D.sup.24                                                                 1.5186                  120   "  "  OCF.sub.3                                                                             CH.sub.3                                                                               "        "   "  "  "     "  n.sub.D.sup.20.5                                                               1.5291                  121   "  "  "      "       n-C.sub.3 H.sub.7                                                                       "   "  "  "     "  n.sub.D.sup.20.5                                                               1.5283                  122   "  "  "      C.sub.2 H.sub.5                                                                        C.sub.2 H.sub.5                                                                         "   "  "  "     "  n.sub.D.sup.20.5                                                               1.5301                  123   "  "  CF.sub.3                                                                              "       "        CH.sub.3                                                                           "  "  "     "  n.sub.D.sup.25                                                                 1.5212                  124   "  "  "      "       "        "   "  "  "     "  n.sub.D.sup.25                                                                 1.5087                  125   "  "  "      CH.sub.3                                                                               "        H   CH.sub.3                                                                          "  "     "  n.sub.D.sup.25.5                                                               1.5209                  126   "  "  "      C.sub.2 H.sub.5                                                                        "        "   "  "  "     "  n.sub.D.sup.25.5                                                               1.5198                  127   "  "  "      CH.sub.3                                                                               CH.sub.2 CHCH.sub.2                                                                     "   H  "  "     "  n.sub.D.sup.23.5                                                               1.5347                  128   CH H  CF.sub.3                                                                              C.sub.2 H.sub.5                                                                        CH.sub.2 CHCH.sub.3                                                                     H   H  H  COOCH.sub.3                                                                          0  n.sub.D.sup.24                                                                 1.5315                  129   "  "  "      n-C.sub.3 H.sub.7                                                                      "        "   "  "  "     "  n.sub.D.sup.24                                                                 1.5291                  130   "  "  OCF.sub.3                                                                             CH.sub.3                                                                               "        "   "  "  "     "  n.sub.D.sup.20.5                                                               1.5341                  131   "  "  "      C.sub.2 H.sub.5                                                                        "        "   "  "  "     "  n.sub.D.sup.20.5                                                               1.5329                  132   "  "  CF.sub.3                                                                              CH.sub.3                                                                               "        CH.sub.3                                                                           "  "  "     "  n.sub.D.sup.25                                                                 1.5268                  133   "  "  "      C.sub.2 H.sub.5                                                                        "        "   "  "  "     "  n.sub.D.sup.25                                                                 1.5208                  134   N  "  "      "       C.sub.2 H.sub.5                                                                         H   H  H  COOC.sub.2 H.sub.5                                                                   "  n.sub.D.sup.20                                                                 1.5423                  135   CH F  "      CH.sub.3                                                                               "        "   "  "  H     "  n.sub.D.sup.25                                                                 1.5311                  __________________________________________________________________________      *111 sodium salt                                                               *112 copper salt                                                               *113 calcium salt                                                              *114 tetrapropylammonium salt hydrate                                          *115 lithium salt                                                              *116 benzyltrimethylammonium salt hydrate                                

Acylcyclohexane, a material, represented by the general formula (II) is produced, for example, by a series of reactions described below: ##STR131## wherein R¹, R², R³, R⁴, R⁵, R⁶, X, Y and Z are as defined above, R⁷ is a (C₁ -C₄)alkyl group and R⁸ is a (C₁ -C₄)alkyl group.

The compound represented by the general formula (VI) is produced by reacting 1 mole of a thiol (IV) with 1 to 1.2 moles of an α,β-unsaturated aldehyde (V) without a solvent or in an inert solvent and under heating or cooling in the presence of a catalyst. The reaction temperature is from 0° C. to the boiling point of the solvent used, preferably from 0° C. to room temperature in the presence of a catalyst. For the catalyst, bases such as triethylamine, alkoxides, etc. are used in an amount of from 0.05 to 0.005 mole equivalent. The solvent includes organic solvents such as alcohol, diethyl ether, tetrahydrofuran (THF), benzene, toluene, chloroform, ethyl acetate, etc. The reaction time is generally from 30 minutes to several hours, and after completion of the reaction, water is added to the reaction solution which is then extracted with an organic solvent. The desired product obtained may be purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (VI) thus obtained are shown in Table 3.

                  TABLE 3                                                          ______________________________________                                         Compounds of the general formula (VI):                                          ##STR132##                                                                    X        Y     Z              R.sup.3                                                                             R.sup.4                                     ______________________________________                                         CH       H     CF.sub.3       H    H                                           CH       H     CF.sub.3       CH.sub.3                                                                            H                                           CH       H     CF.sub.3       H    CH.sub.3                                    CH       H     CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    CH       H     OCF.sub.3      H    H                                           CH       H     OCF.sub.3      CH.sub.3                                                                            H                                           CH       H     OCF.sub.3      H    CH.sub.3                                    CH       H     OCF.sub.3      CH.sub.3                                                                            CH.sub.3                                    CH       H     OCF.sub.2 CF.sub.2 H                                                                          H    H                                           CH       H     OCF.sub.2 CF.sub.2 H                                                                          CH.sub.3                                                                            H                                           CH       H     OCF.sub.2 CF.sub.2 H                                                                          H    CH.sub.3                                    CH       H     OCF.sub.2 CF.sub.2 H                                                                          CH.sub.3                                                                            CH.sub.3                                    N        H     CF.sub.3       H    H                                           N        H     CF.sub.3       CH.sub.3                                                                            H                                           N        H     CF.sub.3       H    CH.sub.3                                    N        H     CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    N        Cl    CF.sub.3       H    H                                           N        Cl    CF.sub.3       CH.sub.3                                                                            H                                           N        Cl    CF.sub.3       H    CH.sub.3                                    N        Cl    CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    ______________________________________                                    

The compound represented by the general formula (VII) is produced by reacting 1 mole of the aldehyde compound (VI) with 1 to 1.1 moles of Wittig reagent represented by the formula, ##STR133## in an inert solvent. The reaction temperature is from 0° C. to the boiling point of the solvent used, preferably from 0° C. to room temperature. The reaction solvent includes organic solvents such as diethyl ether, THF, benzene, toluene, chloroform, dichloromethane, ethyl acetate, etc., and preferably solvents of high solubility such as THF, chloroform, ethyl acetate, etc. are used. The reaction time is generally from 1 to 10 hours, and after completion of the reaction, the solvent is removed and the residue is extracted with a solvent such as hexane, ether, etc. The desired product thus extracted may be purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (VII) thus obtained are shown in Table 4.

                  TABLE 4                                                          ______________________________________                                         Compounds of the general formula (VII):                                         ##STR134##                                                                    X        Y     Z              R.sup.3                                                                             R.sup.4                                     ______________________________________                                         CH       H     CF.sub.3       H    H                                           CH       H     CF.sub.3       CH.sub.3                                                                            H                                           CH       H     CF.sub.3       H    CH.sub.3                                    CH       H     CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    CH       H     OCF.sub.3      H    H                                           CH       H     OCF.sub.3      H    CH.sub.3                                    CH       H     OCF.sub.3      CH.sub.3                                                                            H                                           CH       H     OCF.sub.3      CH.sub.3                                                                            CH.sub.3                                    CH       H     OCF.sub.2 CF.sub.2 H                                                                          H    H                                           CH       H     OCF.sub.2 CF.sub.2 H                                                                          CH.sub.3                                                                            H                                           CH       H     OCF.sub.2 CF.sub.2 H                                                                          H    CH.sub.3                                    CH       H     OCF.sub.2 CF.sub.2 H                                                                          CH.sub.3                                                                            CH.sub.3                                    N        H     CF.sub.3       H    H                                           N        H     CF.sub.3       CH.sub.3                                                                            H                                           N        H     CF.sub.3       H    CH.sub.3                                    N        H     CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    N        Cl    CF.sub.3       H    H                                           N        Cl    CF.sub.3       CH.sub.3                                                                            H                                           N        Cl    CF.sub.3       H    CH.sub.3                                    N        Cl    CF.sub.3       CH.sub.3                                                                            CH.sub.3                                    ______________________________________                                    

The compound represented by the general formula (IX) is produced by reacting 1 mole of the α,β-unsaturated ketone (VII) with 1 to 1.1 moles of dialkyl malonate in the presence of 1 mole of a metal alkoxide and in alcohol or a mixed solvent of alcohol and an inert solvent. The reaction temperature is generally the boiling point of the solvent used. The reaction solvent includes a mixed solvent of an alcohol (e.g. methanol, ethanol) with THF or dioxane and a mixed solvent of an alcohol with benzene or toluene, among which a mixed solvent of methanol with THF is preferably used. The reaction time is generally from 30 minutes to several hours. After completion of the reaction, the precipitated crystals are collected by filtration to obtain the desired compound as a metal salt.

Examples of the compound of the general formula (IX) thus obtained are shown in Table 5.

                  TABLE 5                                                          ______________________________________                                         Compounds of the general formula (IX):                                          ##STR135##                                                                    X     Y     Z           R.sup.3                                                                             R.sup.4                                                                              R.sup.5                                                                             R.sup.6                                ______________________________________                                         CH    H     CF.sub.3    H    H     H    COOCH.sub.3                            CH    H     CF.sub.3    H    CH.sub.3                                                                             "    COOC.sub.2 H.sub.5                     CH    H     CF.sub.3    CH.sub.3                                                                            H     "    "                                      CH    H     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.3   H    H     "    "                                      CH    H     OCF.sub.3   CH.sub.3                                                                            H     "    "                                      CH    H     OCF.sub.3   H    CH.sub.3                                                                             "    COOCH.sub.3                            CH    H     OCF.sub.3   CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       H    H     "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                            H     "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       H    CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      N     H     CF.sub.3    H    H     "    "                                      N     H     CF.sub.3    CH.sub.3                                                                            H     "    "                                      N     H     CF.sub.3    H    CH.sub.3                                                                             "    "                                      N     H     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      N     Cl    CF.sub.3    H    H     "    "                                      N     Cl    CF.sub.3    CH.sub.3                                                                            H     "    COOC.sub.2 H.sub.5                     N     Cl    CF.sub.3    H    CH.sub.3                                                                             "    "                                      N     Cl    CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      CH    H     CF.sub.3    H    H     CH.sub.3                                                                            COOC.sub.2 H.sub.5                     CH    H     CF.sub.3    H    CH.sub.3                                                                             "    "                                      CH    H     CF.sub.3    CH.sub.3                                                                            H     "    "                                      CH    H     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    COOCH.sub.3                            CH    H     OCF.sub.3   H    H     "    "                                      CH    H     OCF.sub.3   CH.sub.3                                                                            H     "    "                                      CH    H     OCF.sub.3   H    CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.3   CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       H    H     "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                            H     "    COOC.sub.2 H.sub.5                     CH    H     OCF.sub.2 CF.sub.2 H                                                                       H    CH.sub.3                                                                             "    "                                      CH    H     OCF.sub.2 CF.sub.2 H                                                                       CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      N     H     CF.sub.3    H    H     "    "                                      N     H     CF.sub.3    CH.sub.3                                                                            H     "    "                                      N     H     CF.sub.3    H    CH.sub.3                                                                             "    "                                      N     H     CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      N     Cl    CF.sub.3    H    H     "    "                                      N     Cl    CF.sub.3    CH.sub.3                                                                            H     "    COOCH.sub.3                            N     Cl    CF.sub.3    H    CH.sub.3                                                                             "    "                                      N     Cl    CF.sub.3    CH.sub.3                                                                            CH.sub.3                                                                             "    "                                      ______________________________________                                    

The compound represented by the general formula (X) is obtained by hydrolyzing the metal salt of the compound represented by the general formula (IX) in water using from 1 to 5 equivalents of an alkali, followed by decarboxylation. The reaction temperature is generally from 90° C. to 100° C. The alkali used includes potassium hydroxide, sodium hydroxide, potassium carbonate, sodium carbonate, etc., and preferably, from 2 to 3 equivalents of sodium carbonate is used. The reaction time is from 1 to several hours. After completion of the reaction, the reaction solution is acidified with hydrochloric acid, and the separated oily product or precipitated crystals are extracted with an organic solvent or filtered off to obtain the desired product. The product may be purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (X) thus obtained are shown in Table 6.

                  TABLE 6                                                          ______________________________________                                         Compounds of the general formula (X):                                           ##STR136##                                                                    X      Y       Z          R.sup.3 R.sup.4                                                                             R.sup.5                                 ______________________________________                                         CH     H       CF.sub.3   H       H    H                                       CH     H       CF.sub.3   CH.sub.3                                                                               H    "                                       CH     H       CF.sub.3   H       CH.sub.3                                                                            "                                       CH     H       CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       CH     H       OCF.sub.3  H       H    "                                       CH     H       OCF.sub.3  CH.sub.3                                                                               H    "                                       CH     H       OCF.sub.3  H       CH.sub.3                                                                            "                                       CH     H       OCF.sub.3  CH.sub.3                                                                               CH.sub.3                                                                            "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      H       H    "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                               H    "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      H       CH.sub.3                                                                            "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                               CH.sub.3                                                                            "                                       N      H       CF.sub.3   H       H    "                                       N      H       CF.sub.3   CH.sub.3                                                                               H    "                                       N      H       CF.sub.3   H       CH.sub.3                                                                            "                                       N      H       CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       N      Cl      CF.sub.3   H       H    "                                       N      Cl      CF.sub.3   H       CH.sub.3                                                                            "                                       N      Cl      CF.sub.3   CH.sub.3                                                                               H    "                                       N      Cl      CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       CH     H       CF.sub.3   H       H    CH.sub.3                                CH     H       CF.sub.3   CH.sub.3                                                                               H    "                                       CH     H       CF.sub.3   H       CH.sub.3                                                                            "                                       CH     H       CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       CH     H       OCF.sub.3  H       H    "                                       CH     H       OCF.sub.3  CH.sub.3                                                                               H    "                                       CH     H       OCF.sub.3  H       CH.sub.3                                                                            "                                       CH     H       OCF.sub.3  CH.sub.3                                                                               CH.sub.3                                                                            "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      H       H    "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                               H    "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      H       CH.sub.3                                                                            "                                       CH     H       OCF.sub.2 CF.sub.2 H                                                                      CH.sub.3                                                                               CH.sub.3                                                                            "                                       N      H       CF.sub.3   H       H    "                                       N      H       CF.sub.3   CH.sub. 3                                                                              H    "                                       N      H       CF.sub.3   H       CH.sub.3                                                                            "                                       N      H       CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       N      Cl      CF.sub.3   H       H    "                                       N      Cl      CF.sub.3   H       CH.sub.3                                                                            "                                       N      Cl      CF.sub.3   CH.sub.3                                                                               H    "                                       N      Cl      CF.sub.3   CH.sub.3                                                                               CH.sub.3                                                                            "                                       ______________________________________                                    

The compound represented by the general formula (XII) is produced by reacting 1 mole of the compound represented by the general formula (IX) or (X) with 1 to 1.1 moles of the acid chloride (XI) in an inert solvent in the presence of 1 to 1.1 moles of a base. The reaction temperature is from 0° C. to room temperature, and the solvent includes organic solvents such as ethers (e.g. diethyl ether, THF, dioxane), benzene, toluene, ethyl acetate, acetone, acetonitrile, etc., among which the ethers are preferably used. The base includes organic bases such as triethylamine, pyridine, N,N-diethylaniline, etc. The reaction time is from 30 minutes to several hours. After completion of the reaction, water is added to the reaction solution which is then extracted with an organic solvent to obtain the desired product. The product may be purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (XII) thus obtained are shown in Table 7.

                                      TABLE 7                                      __________________________________________________________________________     Compounds of the                                                               general formula (XII):                                                          ##STR137##                                                                    X  Y Z      R.sup.3                                                                           R.sup.4                                                                           R.sup.1  R.sup.5                                                                            R.sup.6                                         __________________________________________________________________________     CH H CF.sub.3                                                                              H  H  H        H   H                                               CH H CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H        "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      H   H                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H        "   "                                               CH H CF.sub.3                                                                              CH.sub. 3                                                                         CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       H   H                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub. 2 CF.sub.2 H                                                                 CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               N  H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  H        "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 H   H                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub. 3 H.sub.7                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      H   H                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  H        CH.sub.3                                                                           H                                               CH H CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                           H                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      CH.sub.3                                                                           H                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub. 2 H                                                                 H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               N  H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       CH.sub.3                                                                           H                                               N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  H        "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 CH.sub.3                                                                           H                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.3 H   COOCH.sub.3                                     CH H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   COOC.sub.2 H.sub.5                              CH H CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   COOCH.sub.3                                     CH H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              H  H  H        "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 H   COOCH.sub.3                                     CH H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      H   COOCH.sub.3                                     CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub. 3                                                                            H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.3                                                                             H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CH.sub.2 H                                                                  H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.3 "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               CH H OCF.sub.2 CF.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             H   COOCH.sub.3                                     CH H OCF.sub.2 CH.sub.2 H                                                                  H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.3 "   COOC.sub.2 H.sub.5                              N  H CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   COOCH.sub.3                                     N  H CF.sub. 3                                                                             H  H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   COOC.sub.2 H.sub.5                              N  H CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  H CF.sub.3                                                                              H  CH.sub. 3                                                                         CH(CH.sub.3).sub.2                                                                      "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  H CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              H  H  H        "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  n-C.sub.3 H.sub.7                                                                       H   COOC.sub.2 H.sub.5                              N  Cl                                                                               CF.sub.3                                                                              H  H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                          H  CH.sub.2 OCH.sub.3                                                                      "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               N  H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3 "   "                                               CH H CF.sub.3                                                                              CH.sub.3                                                                          CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.3 "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          C.sub.2 H.sub.5                                                                         "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                       "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH(CH.sub.3).sub.2                                                                      "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 CH(CH.sub.3).sub.2                                                             "   "                                               N  Cl                                                                               CF.sub.3                                                                              H  CH.sub.3                                                                          CH.sub.2 OCH.sub.3                                                                      "   "                                               __________________________________________________________________________

The compound represented by the general formula (II)' is obtained by heating the compound represented by the general formula (XII) in the presence of a catalyst. The reaction temperature is from 50° to 150° C., preferably in the vicinity of 100° C. For the solvent, organic solvents such as THF, chloroform, acetonitrile, benzene, toluene, etc. are used. The catalyst includes Lewis acids (e.g. zinc chloride), bases (e.g. 4-dimethylaminopyridine) and acids (e.g. trifluoromethanesulfonic acid), among which the bases are preferably used. The reaction generally comes to an end in several hours. After completion of the reaction, the reaction solution is poured into water, acidified and then extracted with an organic solvent to obtain the desired product. This product may be purified if necessary by recrystallization or column chromatography.

Examples of the compound of the general formula (II)' thus obtained are shown in Table 8.

                                      TABLE 8                                      __________________________________________________________________________     Compounds of the general formula (II)':                                         ##STR138##                                                                    X  Y  Z      R.sup.3                                                                            R.sup.4                                                                            R.sup.1  R.sup.5                                                                           R.sup.6                                       __________________________________________________________________________     CH H  CF.sub.3                                                                              H   H   CH.sub.3 H  H                                             CH H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   H        "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   H        "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      H  H                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           H        "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                       ""                                               CH H  OCF.sub.3                                                                             H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                       H  H                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH(CH.sub.3 .sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                               CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 H  H                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              CH.sub. 3                                                                          H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      H  H                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub. 3                                                                          CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.3 CH.sub.3                                                                          "                                             CH H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   H        "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      CH.sub.3                                                                          H                                             CH H  CF.sub. 3                                                                             H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.3                                                                          H                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub. 3 H.sub.7                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      CH.sub.3                                                                          H                                             N  H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   H        "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         CH.sub.3                                                                          H                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.3 H  COOCH.sub.3                                   CH H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  COOC.sub.2 H.sub.5                            CH H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  COOCH.sub.3                                   CH H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   H   H        "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         H  COOCH.sub.3                                   CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      H  COOCH.sub.3                                   CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      H  COOCH.sub.3                                   CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             CH H  OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.3 "  COOC.sub.2 H.sub.5                            N  H  CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  COOCH.sub.3                                   N  H  CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  COOC.sub.2 H.sub.5                            N  H  CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   H   H        "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  H  CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.3 H  COOC.sub.2 H.sub.5                            N  Cl CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H    CH(CH.sub.3).sub.2                                                                     "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 OCH.sub.3                                                                      "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             N  H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3 "  "                                             CH H  CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3 "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                         "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                       "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                      "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                             "  "                                             N  Cl CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 OCH.sub.3                                                                      "  "                                             __________________________________________________________________________

The compound represented by the formula (II)" is produced by oxidation of the acylcyclohexane represented by the general formula (II)'. The oxidation reaction can be performed by using a usual method, for example, m-chloroperbenzoic acid in chloroform, hydrogen peroxide in acetic acid, etc.

The number of n is controlled by amount of the oxidant used and the reaction temperature. After completion of the reaction, which is generally required one to several hours, the reaction solution is poured into water, extracted with an organic solvent to obtain the desired product. This product may be purified, if necessary, by recrystallization or column chromatography.

Examples of the compound of the general formula (II)" thus obtained are shown in Tables 9 and 10.

                                      TABLE 9                                      __________________________________________________________________________     Compounds of the general formula (II)":                                         ##STR139##                                                                    X  Y Z      R.sup.3                                                                            R.sup.4                                                                            R.sup.1   R.sup.5                                                                           R.sup.6                                       __________________________________________________________________________     CH H CF.sub.3                                                                              H   H   CH.sub.3  H  H                                             CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             CH H CF.sub.3                                                                              H   H   H         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   H         "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           H         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                        H  H                                             CH H OCF.sub.3                                                                             H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   H(CH.sub.3).sub.2                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              H  H                                             N  H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub. 3                                                                             H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             N  H CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH(CH.sub.3).sub.2                                                                       "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        H  H                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H CF.sub.3                                                                              H   H   H         CH.sub.3                                                                          "                                             CH H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH(CH.sub.3).sub.2                                                                       "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.2 CH(CH.sub.3).sub.2                                                              CH.sub.3                                                                          H                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  CH.sub.3                                                                          H                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub. 5                                                                         "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  CH.sub.3                                                                          H                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub. 3                                                                          CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.3  H  COOCH.sub.3                                   CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  COOC.sub.2 H.sub.5                            CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  COOCH.sub.3                                   CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          H  COOCH.sub.3                                   CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        H  COOCH.sub.3                                   N  H CF.sub.3                                                                              H   H   CH.sub.3  "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  COOCH.sub.3                                   N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub. 3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             __________________________________________________________________________

                                      TABLE 10                                     __________________________________________________________________________     Compounds of the general formula (II)":                                         ##STR140##                                                                    X  Y Z      R.sup.3                                                                            R.sup.4                                                                            R.sup.1   R.sup.5                                                                           R.sup.6                                       __________________________________________________________________________     CH H CF.sub.3                                                                              H   H   CH.sub.3  H  H                                             CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH(CH.sub.3).sub.2                                                                       "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.2 CH(CH.sub.3).sub.2                                                              "  "                                             CH H CF.sub.3                                                                              H   H   H         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub. 2 H.sub.5                                                                         "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        H  H                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub. 3                                                                          H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          H  H                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH N CF.sub.3                                                                              CH.sub.3                                                                           CH.sub. 3                                                                          C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.3  CH.sub.3                                                                          "                                             CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          CH.sub.3                                                                          H                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  CH.sub.3                                                                          H                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  CH.sub.3                                                                          H                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.3  H  COOCH.sub.3                                   CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub. 5                                                                         "  COOC.sub.2 H.sub.5                            CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  COOCH.sub.3                                   CH H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H CF.sub.3                                                                              H   H   CH.sub.3  "  "                                             CH H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   CH.sub.3  H  COOCH.sub.3                                   CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.3                                                                             H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           CH.sub.3  "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H OCF.sub.2 CF.sub.2 H                                                                  H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   H   CH.sub.3  "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  COOCH.sub.3                                   N  H CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  COOC.sub.2 H.sub.5                            N  H CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          H  "                                             N  H CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        H  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   CH.sub.3  H  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              CH.sub.3                                                                           H   n-C.sub.3 H.sub.7                                                                        "  "                                             N  H CF.sub.3                                                                              CH.sub. 3                                                                          CH.sub.3                                                                           CH.sub.3  "  "                                             N  H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           CH.sub.3  "  "                                             CH H CF.sub.3                                                                              CH.sub.3                                                                           CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           CH.sub.3  "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           C.sub.2 H.sub.5                                                                          "  "                                             N  Cl                                                                               CF.sub.3                                                                              H   CH.sub.3                                                                           n-C.sub.3 H.sub.7                                                                        "  "                                             __________________________________________________________________________

PRODUCTION EXAMPLE 10 Production of the compound (VI) Production of 3-(4-trifluoromethylphenylthio)propionaldehyde

Ten grams of 4-trifluoromethylthiophenol was dissolved in 15 ml of THF, and after adding 4.0 g of 95% acrolein under ice-cooling, 0.1 g of triethylamine was added while thoroughly stirring the reaction solution. After stirring for 1.5 hours under ice-cooling, the reaction solution was poured into water and extracted with ether. The ether layer was washed with water and dried over anhydrous magnesium sulfate. The solvent was removed under reduced pressure to obtain 13.1 g of 3-(4-trifluoromethylphenylthio)propionaldehyde.

¹ H-NMR (CDCl₃): δ (ppm) 9.81 (1H, s) 7.47 (4H, ABq), 3.25 (2H, t), 2.84 (2H, t).

Examples of the compound of the general formula (VI) thus produced are shown in Table 11.

                  TABLE 11                                                         ______________________________________                                         Compounds of the general formula (VI):                                          ##STR141##                                                                                                         Physical                                  X     Y       Z           R.sup.3                                                                              R.sup.4                                                                             property                                  ______________________________________                                         CH    H       CF.sub.3    CH.sub.3                                                                             H    n.sub.D.sup.21 1.5043                     CH    H       CF.sub.3    H     CH.sub.3                                                                            n.sub.D.sup.22 1.5020                     CH    H       OCF.sub.3   H     H    n.sub.D.sup.29 1.4886                     CH    H       OCF.sub.2 CF.sub.2 H                                                                       H     H    n.sub.D.sup.23 1.4771                     N     H       CF.sub.3    H     H    n.sub.D.sup.22 1.5228                     N     Cl      CF.sub.3    H     H    n.sub.D.sup.19 1.5262                     ______________________________________                                    

PRODUCTION EXAMPLE 11 Production of the compound (VII) Production of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one

Ten grams of 3-(4-trifluoromethylphenylthio)propionaldehyde and 15 g of triphenylphosphine acetylmethylene were dissolved in 50 ml of chloroform, followed by stirring for 8 hours under ice-cooling. After removing chloroform, ether was added to the residue, and ether-insoluble products were removed by filtration. The ether-soluble product was purified by column chromatography (eluent; ethyl acetate: hexane=1:3) to obtain 9.9 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one.

¹ H-NMR (CDCl₃): δ (ppm) 7.46 (4H, ABq), 6.79 (1H, dt), 6.11 (1H, d), 3.3-2.5 (4H, m), 2.22 (3H, s).

Examples of the compound of the general formula (VII) thus produced are shown in Table 12.

                  TABLE 12                                                         ______________________________________                                         Compounds of the general formula (VII):                                         ##STR142##                                                                                                         Physical                                  X     Y       Z           R.sup.3                                                                              R.sup.4                                                                             property                                  ______________________________________                                         CH    H       CF.sub.3    CH.sub.3                                                                             H    n.sub.D.sup.21 1.5101                     CH    H       CF.sub.3    H     CH.sub.3                                                                            n.sub.D.sup.23 1.5077                     CH    H       OCF.sub.3   H     H    n.sub.D.sup.26 1.5011                     CH    H       OCF.sub.2 CF.sub.2 H                                                                       H     H    n.sub.D.sup.23 1.5002                     N     H       CF.sub.3    H     H    n.sub.D.sup.22 1.5162                     N     Cl      CF.sub.3    H     H    n.sub.D.sup.19 1.5332                     ______________________________________                                    

PRODUCTION EXAMPLE 12 Production of the compound (IX) Production of the sodium salt of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione

2.32 Grams of sodium was dissolved in 30 ml of methanol, and 300 ml of THF and 13.5 g of dimethyl malonate were added in this order. Heating under reflux was then carried out for 15 minutes, removed oil bath, and after adding 27.42 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one, heating under reflux was again carried out for 30 minutes. The reaction solution was cooled to room temperature, and the precipitated crystals were filtered off and thoroughly washed with ether and hexane to obtain 34.3 g of the sodium salt of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (D₂ O): δ (ppm) 7.45 (4H, ABq), 5.35 (1H, s), 3.88 (3H, s), 3.01 (2H, t), 2.5-1.5 (6H, m).

Examples of the compound of the general formula (IX) thus produced are shown in Table 13.

                  TABLE 13                                                         ______________________________________                                         Sodium salt of the compounds of the general formula (IX):                       ##STR143##                                                                                                             Physical                                                                       property                              X    Y     Z         R.sup.3                                                                             R.sup.4                                                                             R.sup.5                                                                             R.sup.7                                                                             (.sup.1 H-NMR)                        ______________________________________                                         CH   H     CF.sub.3  H    H    H    CH.sub.3                                                                            7.45(4H, ABq),                                                                 5.35 (1H, s),                                                                  3.88 (3H, s),                                                                  3.01(2H, t),                                                                   2.5-1.5(6H, m)                        CH   H     CF.sub.3  CH.sub.3                                                                            H    H    CH.sub.3                                                                            7.43(4H, brs),                                                                 5.21 (1H, s),                                                                  3.87(3H, s),                                                                   3.35(1H, q),                                                                   1.29(3H, d),                                                                   2.5-1.5 (6H, m)                       CH   H     CF.sub.3  H    CH.sub.3                                                                            H    CH.sub.3                                                                            7.40(4H, ABq),                                                                 5.15(1H, s),                                                                   3.78 (3H, s),                                                                  2.90 (2H, d),                                                                  1.10 (3H, d),                                                                  2.5-1.5 (5H, m)                       CH   H     OCF.sub.3 H    H    H    CH.sub.3                                                                            7.42(4H, ABq),                                                                 5.11(1H, s),                                                                   3.82(3H, s),                                                                   3.00(2H, t),                                                                   2.5-1.5 (6H, m)                       CH   H     OCF.sub.2 CF.sub.2 H                                                                     H    H    H    CH.sub.3                                                                            7.40(4H, ABq),                                                                 5.85(1H, tt),                                                                  5.10(1H, s),                                                                   3.79(3H, s),                                                                   3.05(2H, t),                                                                   2.5-1.5(6H, m)                        N    H     CF.sub.3  H    H    H    CH.sub. 3                                                                           8.62(1H, s),                                                                   7.76(1H, dd),                                                                  7.22(1H, d),                                                                   5.22 (1H, s),                                                                  3.81(3H, s),                                                                   3.01(2H, s),                                                                   2.5-1.5(6H, m)                        N    Cl    CF.sub.3  H    H    H    CH.sub.3                                                                            8.65(1H, brs),                                                                 7.80 (1H, brs),                                                                5.25(1H,s),                                                                    3.78(3H, s),                                                                   3.02 (2H, t),                                                                  2.5-1.5(6H, m)                        CH   H     CF.sub.3  H    H    CH.sub.3                                                                            CH.sub.3                                                                            7.42(4H, ABq),                                                                 5.34(1H, s),                                                                   3.86(3H, s),                                                                   2.99 (2H, t),                                                                  2.5-1.5(5H, m),                                                                1.10(3H, s)                           ______________________________________                                    

PRODUCTION EXAMPLE 13 Production of the compound (X) Production of 5-[2-(4-trifluoromethylphenylthio)-ethyl]cyclohexane-1,3-dione

2.00 Grams of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 30 ml of water, and 1.6 g of sodium carbonate was added to the resulting solution which was then heated under reflux for 5 hours. After thoroughly cooling the reaction solution, the reaction solution was extracted with ether to remove impurities, and the aqueous layer was acidified with hydrochloric acid and extracted with ethyl acetate to separate the desired product. The ethyl acetate layer was dried over anhydrous magnesium sulfate, and after removing ethyl acetate, the resulting crystals were washed with hexane to obtain 1.5 g of 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (CDCl₃ +DMSO-d₆): δ (ppm) 7.44 (4H, q), 5.32 (1H, s), 2.99 (2H, t), 2.5-1.5 (7H, m).

Examples of the compound of the general formula (X) thus produced are shown in Table 14.

                  TABLE 14                                                         ______________________________________                                         Compounds of the general formula (X):                                           ##STR144##                                                                                                         Physical                                  X    Y     Z          R.sup.3                                                                             R.sup.4                                                                             R.sup.5                                                                             property (.sup.1 H-NMR)                   ______________________________________                                         CH   H     CF.sub.3   H    H    H    7.44(4H, ABq),                                                                 5.32(1H, s),                                                                   2.99(2H, t), 2.5-1.5                                                           (7H, m)                                   CH   H     CF.sub.3   CH.sub.3                                                                            H    H    7.45(4H, brs),                                                                 5.15(1H, s), 3.25(1H,                                                          m), 1.17(3H, d),                                                               2.5-1.5(7H, m)                            CH   H     CF.sub.3   H    CH.sub.3                                                                            H    7.42(4H, ABq),                                                                 5.10(1H, s),                                                                   2.95(2H, d), 1.11(3H,                                                          d), 2.5-1.5(6H, m)                        CH   H     OCF.sub.3  H    H    H    7.40(4H, ABq),                                                                 5.21(1H, s),                                                                   3.03(2H, t), 2.5-1.5                                                           (7H, m)                                   CH   H     OCF.sub.2 CF.sub.2 H                                                                      H    H    H    7.41(3H, s), 5.82(1H,                                                          tt), 5.22(1H, s),                                                              3.08(2H, t), 2.5-1.5                                                           (7H, m)                                   N    H     CF.sub.3   H    H    H    8.60(1H, s), 7.75(1H,                                                          dd), 7.24(1H, s),                                                              3.01(2H, s), 2.5-1.5                                                           (7H, m)                                   N    Cl    CF.sub.3   H    H    H    8.63(1H, brs),                                                                 7.75(1H, brs),                                                                 3.02(2H, t), 2.5-1.5                                                           (7H, m)                                   CH   H     CF.sub.3   H    H    CH.sub.3                                                                            7.43(4H, ABq),                                                                 5.31(1H, s),                                                                   2.95(2H, t), 2.5-1.5                                                           (6H, m), 1.15(3H, d)                      ______________________________________                                    

PRODUCTION EXAMPLE 14 Production of the compound (XII) Production of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one

6.32 Grams of 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 50 ml of tetrahydrofuran, and 2.12 g of triethylamine was added. Thereafter, 1.73 g of acetyl chloride was added dropwise with thorough stirring under ice-cooling. After continuing stirring for further 2 hours at room temperature, the precipitated solid was filtered off. The solvent was removed from the filtrate, and the residue was dissolved in ether. The ether layer was successively washed with dilute hydrochloric acid, aqueous sodium hydrogencarbonate and water and dried over anhydrous magnesium sulfate. Ether was removed to obtain 7.13 g of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one.

¹ H-NMR (CDCl₃): δ (ppm) 7.39 (4H, q), 5.86 (1H, s), 3.07 (2H, t), 2.16 (3H, s), 2.5-1.5 (7H, m).

Examples of the compound of the general formula (XII) thus produced are shown in Table 15.

                                      TABLE 15                                     __________________________________________________________________________     Compounds of the general formula (XII):                                         ##STR145##                                                                                                       Physical                                    X  Y Z      R.sup.3                                                                           R.sup.4                                                                           R.sup.5                                                                           R.sup.6                                                                              R.sup.1 property                                    __________________________________________________________________________     CH H CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.20 1.5115                       CH H CF.sub.3                                                                              H  H  CH.sub.3                                                                          H     CH.sub.3                                                                               n.sub.D.sup.20 1.5098                       CH H CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        m.p. 47-48° C.                       CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.20 1.5058                       CH H CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.19 1.4995                       CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.19 1.5216                       CH H CF.sub.3                                                                              H  H  H  H     CH(CH.sub.3).sub.2                                                                     n.sub.D.sup.20 1.5383                       CH H CF.sub.3                                                                              H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                                                            m.p. 64-65° C.                       CH H CF.sub.3                                                                              H  H  H  H     CH.sub.2 OCH.sub.3                                                                     n.sub.D.sup.22.5 1.5341                     CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.20 1.5401                       CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.23 1.5512                       CH H CF.sub.2                                                                              CH.sub.3                                                                          H  H  H     CH.sub.3                                                                               n.sub.D.sup.22.5 1.5326                     CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.23 1.5486                       CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.22.5 1.5162                     CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.23 1.4979                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.24 1.5429                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  H     CH.sub.3                                                                               n.sub.D.sup.24 1.5416                       CH H CF.sub. 3                                                                             H  CH.sub.3                                                                          H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.24 1.5326                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.24 1.5433                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.22 1.4165                       CH H OCF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.26 1.5501                       CH H OCF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.26 1.5385                       CH H OCF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.27.5 1.5118                     CH H OCF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.27.5 1.4911                     CH H OCF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.25 1.5281                       CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.24 1.5211                       CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.24 1.5081                       CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.24 1.4944                       N  H CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.21 1.5561                       N  H CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.21 1.5537                       N  H CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.21 1.5121                       N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.22.5 1.5485                     N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.22.5 1.5315                     N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.22.5 1.5067                     N  H CF.sub.3                                                                              H  H  H  H     CH.sub.2 OCH.sub.3                                                                     n.sub.D.sup.23 1.5135                       N  H CF.sub.3                                                                              H  H  H  COOC.sub.2 H.sub.5                                                                   C.sub.2 H.sub.5                                                                        n.sub.D.sup.24 1.5417                       __________________________________________________________________________

PRODUCTION EXAMPLE 15 Production of the compound (II)' Production of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione

3.3 Grams of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one and 0.8 g of 4-dimethylaminopyridine were dissolved in acetonitrile, followed by heating under reflux for 2.5 hours. After removing acetonitrile, the residue was dissolved in ethyl acetate, and the ethyl acetate layer was washed with dilute hydrochloric acid and then with water, and dried over anhydrous magnesium sulfate. Ethyl acetate was removed to obtain 3.3 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione.

¹ H-NMR (CDCl₃): δ (ppm) 18.16 (1H, s), 7.46 (4H, q), 3.03 (2H, t), 2.58 (3H, s), 2.8-1.6 (7H, m).

Examples of the compound of the general formula (II)' thus produced are shown in Table 16.

                                      TABLE 16                                     __________________________________________________________________________     Compounds of the general formula (II)':                                         ##STR146##                                                                                                       Physical                                    X  Y Z      R.sup.3                                                                           R.sup.4                                                                           R.sup.5                                                                           R.sup.6                                                                              R.sup.1 property                                    __________________________________________________________________________     CH H CF.sub.3                                                                              H  H  CH.sub.3                                                                          H     CH.sub.3                                                                               n.sub.D.sup.24 1.5231                       CH H CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               m.p. 60-61° C.                       CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.24 1.5465                       CH H CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.25 1.5161                       CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.24 1.5399                       CH H CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.25 1.5017                       CH H CF.sub.3                                                                              H  H  H  COOCH.sub.3                                                                          n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.23 1.5178                       CH H CF.sub.3                                                                              H  H  H  H     CH(CH.sub.3).sub.2                                                                     n.sub.D.sup.23 1.5261                       CH H CF.sub.3                                                                              H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                                                            n.sub.D.sup.24 1.5362                       CH H CF.sub.3                                                                              H  H  H  H     CH.sub.2 OCH.sub.3                                                                     n.sub.D.sup.23 1.5412                       CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.23 1.5450                       CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  H     CH.sub.3                                                                               n.sub.D.sup.25.5 1.5288                     CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.23 1.5392                       CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.25.5 1.5026                     CH H CF.sub.3                                                                              CH.sub.3                                                                          H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.22.5 1.4879                     CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.23 1.5410                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  H     CH.sub.3                                                                               n.sub.D.sup.25.5 1.4852                     CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  H     C.sub.2 H.sub.5                                                                        D.sub.D.sup.25.5 1.4967                     CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.23 1.5351                       CH H CF.sub.3                                                                              H  CH.sub.3                                                                          H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.26 1.4801                       CH H OCF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                          CH.sub.3                                                                               n.sub.D.sup.25 1.5320                       CH H OCF.sub.3                                                                             H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.26 1.5239                       CH H OCF.sub.3                                                                             H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.26.5 1.5113                     CH H OCF.sub.3                                                                             H  H  H  COOCH.sub.3                                                                          C.sub.2 H.sub.5                                                                        n.sub.D.sup.25 1.5448                       CH H OCF.sub.3                                                                             H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.26.5 1.5099                     CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.26.5 1.5276                     CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.26.5 1.5146                     CH H OCF.sub.2 CF.sub.2 H                                                                  H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.26.5  1.4878                    N  H CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.25.5 1.5325                     N  H CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.25.5 1.5150                     N  H CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.25.5 1.4949                     N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     CH.sub.3                                                                               n.sub.D.sup.26 1.5437                       N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     C.sub.2 H.sub.5                                                                        n.sub.D.sup.26 1.5339                       N  Cl                                                                               CF.sub.3                                                                              H  H  H  H     n-C.sub.3 H.sub.7                                                                      n.sub.D.sup.26 1.5201                       N  H CF.sub.3                                                                              H  H  H  H     CH.sub.2 OCH.sub.3                                                                     n.sub.D.sup.25 1.5286                       N  H CF.sub.3                                                                              H  H  H  COOC.sub.2 H.sub.5                                                                   C.sub.2 H.sub.5                                                                        n.sub.D.sup.25 1.5472                       __________________________________________________________________________

PRODUCTION EXAMPLE 16 Production of the compound (II)" Production of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]cyclohexane-1,3-dione

To a solution of 2.0 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione in 10 ml of acetic acid, 3.2 g of 30% hydrogen peroxide was added. The solution was stirred for 3 hours at 80° C. The solution was poured into water and extracted with ethyl acetate. Removal of solvent afforded 1.6 g of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]-cyclohexane-1,3-dione. m.p. 135.5°-136.5° C.

¹ H-NMR (acetone-d₆): δ (ppm) 18-19 (1H, br), 7.75 (4H, ABq), 3.12 (2H, t), 2.20 (3H, s), 2.2-1.4 (7H, m)

Production of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione

To a solution of 2.3 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione in 10 ml of acetic acid, 1.8 g of 30% H₂ O₂ was dropped under cooling with ice-water bath. After stirring for 1 hour at room temperature, the reaction solution was poured into water and extracted with ethyl acetate. Removal of solvent afforded 1.83 g of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione. m.p. 99°-100° C.

¹ H-NMR (acetone-d₆): δ (ppm) 18.10 (1H, s), 7.84 (4H, s), 2.90 (2H, t), 2.59 (3H, s), 3-1.6 (7H, m).

Examples of the compound of the general formula (II)" thus produced are shown in Table 17.

                  TABLE 17                                                         ______________________________________                                         Compounds of the General formula (II)":                                         ##STR147##                                                                                                                   Physical                        X    Y     Z      R.sub.1                                                                             R.sub.2                                                                            R.sub.3                                                                            R.sub.4                                                                            R.sub.5                                                                            R.sub.6                                                                            n   properties                      ______________________________________                                         CH   H     CF.sub.3                                                                              CH.sub.3                                                                            H   H   H   H   H   1   m.p. 99-100° C.          CH   H     CF.sub.3                                                                              CH.sub.3                                                                            H   H   H   H   H   2   m.p. 135.5-                                                                    136.5° C.                CH   H     CF.sub.3                                                                              C.sub.2 H.sub.5                                                                     H   H   H   H   H   1   m.p. 105-                                                                      106° C.                  CH   H     CF.sub.3                                                                              C.sub.2 H.sub.5                                                                     H   H   H   H   H   2   m.p. 140-                                                                      141° C.                  ______________________________________                                    

When the present compounds are used as an active ingredient for herbicides, they are generally formulated into emulsifiable concentrates, wettable powders, suspension formulations, granules, etc. by mixing with solid carriers, liquid carriers, surface active agents and other auxiliaries for formulation.

These preparations contain from 0.1 to 90% by weight, preferably from 0.2 to 80% by weight, more preferably from 1 to 80% by weight of the present compounds as an active ingredient.

The solid carriers include fine powders or granules of kaolin clay, attapulgite clay, bentonite, terra abla, pyrophyllite, talc, diatomaceous earth, calcite, walnut powder, urea, ammonium sulfate, synthetic hydrated silicon dioxide, etc. The liquid carriers include aromatic hydrocarbons (e.g. xylene, methylnaphthalene), alcohols (e.g. isopropanol, ethylene glycol, cellosolve), ketones (e.g. acetone, cyclohexanone, isophorone), vegetable oils (e.g. soybean oil, cotton seed oil), dimethyl sulfoxide, N,N-dimethylformamide, acetonitrile, water, etc.

The surface active agents used for emulsification, dispersion, wetting, etc. include anionic surface active agents such as the salt of alkyl sulfates, alkylsulfonates, alkylarylsulfonates, dialkyl sulfosuccinates, the salt of polyoxyethylene alkylaryl ether phosphoric acid ester, etc., and nonionic surface active agents such as polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene polyoxypropylene block copolymers, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, etc.

The auxiliaries for formulation include lignosulfonates, alginates, polyvinyl alcohol, gum arabic, CMC (carboxymethyl cellulose), PAP (isopropyl acid phosphate), etc.

Next, formulation examples will be shown. The present compounds are shown by Compound No. in Table 2. Parts in the examples are by weight.

FORMULATION EXAMPLE 1

Fifty parts of the present compound (4) or (7), 3 parts of calcium lignoinsulfonate, 2 parts of sodium lauryl sulfate and 45 parts of synthetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder.

FORMULATION EXAMPLE 2

Ten parts of each of the present compound (1)-(134), 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of calcium dodecylbenzenesulfonate, 30 parts of xylene and 40 parts of cyclohexanone are well mixed to obtain an emulsifiable concentrate.

FORMULATION EXAMPLE 3

One part of the present compound (9) or (10), 1 part of synthetic hydrated silicon dioxide, 2 parts of calcium lignosulfonate, 31 parts of bentonite and 65 parts of kaolin clay are well pulverized and mixed together, well kneaded with water, granulated and dried to obtain a granule.

FORMULATION EXAMPLE 4

Twenty-five parts of the present compound (11), 3 parts of polyoxyethylene sorbitan monooleate, 3 parts of CMC and 69 parts of water are mixed and wet-pulverized until the particle size is reduced to 5 microns or less to obtain a suspension formulation.

FORMULATION EXAMPLE 5

Eighty parts of the present compound (1), 3 parts of calcium lignosulfonate, 2 parts of sodium lauryl sulfate and 15 parts of synthetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder.

FORMULATION EXAMPLE 6

Twenty parts of the present compound (76), 2 parts of calcium lignosulfonate, 3 parts of alkylsulfonate and 10 parts of synthetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder.

FORMULATION EXAMPLE 7

Two parts of the present compound (82), 1 part of polyoxyethylene sorbitan monooleate, 5 parts of polyvinyl alcohol and 92 parts of water are mixed and wet-pulverized until the particle size is reduced to 5 microns or less to obtain a suspension formulation.

FORMULATION EXAMPLE 8

Twenty parts of the present compound (5), 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of calcium dodecylbenzenesulfonate, 30 parts of xylene and 30 parts of isophorone are well mixed to obtain an emulsifiable concentrate.

Generally, the present compounds are formulated and used in soil treatment, foliage treatment or treatment under flooded condition before or after the emergence of weeds. The soil treatment includes soil surface treatment, soil incorporation treatment, etc., and the foilage treatment includes, in addition to the treatment of plants over the top, directed treatment wherein herbicides are applied to weeds only so as not to attach to crops.

Further, the present compounds can be used as a herbicide for paddy fields, plow fields, orchards, pastures, turfs, forests, non-crop lands, etc., and also an increase in herbicidal activity can be expected by using them in mixture with other herbicides. In addition, they can be used in mixture with insecticides, acaricides, nematocides, plant growth regulators, fertilizers, soil improvers, etc.

When the present compounds are used as an active ingredient for herbicides, their dosage rate varies with weather conditions, preparation forms, when, how and where the treatments are applied, weeds and crops aimed at, etc., but it is generally from 0.05 to 200 g/are, preferably from 0.1 to 100 g/are. The usual dosage is from 0.6 to 10 g/are before the emergence of weeds. It is from 0.1 to 4 g/are after the emergence of weeds and is preferably from 0.2 to 2 g/are especially in corn and wheat field. It is from 0.1 to 4 g/are in paddy field and is from 10 to 100 g/are in orchards, forests and non-crop lands. In the case of emulsifiable concentrates, wettable powders, suspension formulations, etc., their prescribed amount is generally diluted with water of from 1 to 10 liters/are (if necessary, auxiliaries such as spreading agents are added). Granules, etc. are generally used as such without dilution.

The spreading agents include, in addition to the foregoing surface active agents, polyoxyethylene resin acid (ester), lignosulfonates, abietates, dinaphthylmethanedisulfonates, paraffin, etc.

Next, the usefulness of the present compounds as an active ingredient for herbicides will be illustrated with reference to the following test examples. In the test examples, the present compounds are shown by Compound No. in Table 2, and compounds used as a control are shown by Compound symbol in Table 18.

                                      TABLE 18                                     __________________________________________________________________________     Compound                                                                       symbol                                                                               Structural formual              Remark                                   __________________________________________________________________________     (A)                                                                                   ##STR148##                     Compound described in Japanese                                                 Patent Publication Kokai                                                       (Laid-open) No. 46749/1979.              (B)                                                                                   ##STR149##                     Compound described in Japanese                                                 Patent Publication Kokai                                                       (Laid-open) No. 115349/1979.             (C)                                                                                   ##STR150##                                                              (D)                                                                                   ##STR151##                     Atrazine                                 (E)                                                                                   ##STR152##                     Simetryn                                 (F)                                                                                   ##STR153##                     Sethoxydim                               __________________________________________________________________________

The herbicidal activity and phytotoxicity were evaluated in six stages, 0, 1, 2, 3, 4, 5, according to the states of the emergence and growth of test plants (weeds and crops) at the time of examination. A stage "0" means there being little or no difference in the states between the treated test plants and untreated ones; a stage "5" means the complete death of test plants or complete inhibition of the emergence or growth thereof; and the states between "0" and "5" were divided into four stages, 1, 2, 3 and 4.

TEST EXAMPLE 1 Soil surface treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the weeds of Japanese millet and oat were sowed and covered with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 19.

                  TABLE 19                                                         ______________________________________                                         Compound  Dosage      Herbicidal activity                                      No.       (g/are)     Japanese millet                                                                            Oat                                          ______________________________________                                          2        40          5           5                                             3        40          5           --                                           10        40          5           5                                            11        40          5           5                                            12        40          5           5                                            13        40          5           --                                           20        40          5           5                                            21        40          5           5                                            22        40          5           5                                            23        40          5           5                                            24        40          5           --                                           25        40          5           --                                           26        40          5           5                                            27        40          5           --                                           28        40          5           --                                           30        40          5           5                                            31        40          5           5                                            32        40          5           5                                            33        40          5           5                                            34        40          5           --                                           41        40          5           --                                           43        40          5           --                                           44        40          5           5                                            51        40          5           5                                            52        40          5           --                                           53        40          5           5                                            54        40          5           5                                            55        40          5           5                                            56        40          5           5                                            57        40          5           --                                           58        40          5           --                                           59        40          5           5                                            60        40          5           5                                            67        40          5           5                                            68        40          5           5                                            69        40          5           5                                            70        40          5           5                                            71        40          5           5                                            72        40          5           5                                            73        40          5           5                                            74        40          5           5                                            75        40          5           5                                            76        40          5           5                                            77        40          5           5                                            78        40          5           5                                            79        40          5           5                                            80        40          5           5                                            81        40          5           5                                            82        40          5           5                                            83        40          5           5                                            84        40          5           5                                            85        40          5           5                                            86        40          5           5                                            87        40          5           5                                            88        40          5           5                                            89        40          5           5                                            90        40          5           5                                            91        40          5           5                                            92        40          5           5                                            93        40          5           5                                            94        40          5           --                                           95        40          5           5                                            97        40          5           5                                            98        40          5           5                                            99        40          5           5                                            100       40          5           5                                            101       40          5           5                                            102       40          5           5                                            103       40          5           5                                            104       40          5           5                                            105       40          5           5                                            106       40          5           5                                            107       40          5           5                                            108       40          5           5                                            109       40          5           5                                            110       40          5           5                                            111       40          5           5                                            112       40          5           5                                            114       40          5           5                                            ______________________________________                                    

TEST EXAMPLE 2 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of Japanese millet and oat were sowed and cultivatied for 10 days in a greenhouse. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 20.

                  TABLE 20                                                         ______________________________________                                         Compound  Dosage      Herbicidal activity                                      No.       (g/are)     Japanese millet                                                                            Oat                                          ______________________________________                                          1        40          5           5                                             2        40          5           5                                             3        40          5           5                                             4        40          5           5                                             5        40          5           5                                             6        40          5           5                                             7        40          5           5                                             8        40          5           5                                             9        40          5           5                                            10        40          5           5                                            11        40          5           5                                            12        40          5           5                                            13        40          5           5                                            14        40          5           5                                            15        40          5           5                                            16        40          5           5                                            17        40          5           5                                            18        40          5           5                                            19        40          5           5                                            20        40          5           5                                            21        40          5           5                                            22        40          5           5                                            23        40          5           5                                            24        40          5           5                                            25        40          5           5                                            26        40          5           5                                            27        40          5           5                                            28        40          5           5                                            29        40          5           5                                            30        40          5           5                                            40        40          5           5                                            41        40          5           5                                            42        40          5           5                                            43        40          5           5                                            44        40          5           5                                            45        40          5           5                                            46        40          5           5                                            47        40          5           5                                            48        40          5           5                                            49        40          5           5                                            50        40          5           5                                            51        40          5           5                                            52        40          5           5                                            53        40          5           5                                            54        40          5           5                                            55        40          5           5                                            56        40          5           5                                            57        40          5           5                                            58        40          5           5                                            59        40          5           5                                            60        40          5           5                                            61        40          5           5                                            62        40          5           5                                            63        40          5           5                                            64        40          5           5                                            65        40          5           5                                            66        40          5           5                                            67        40          5           5                                            68        40          5           5                                            69        40          5           5                                            70        40          5           5                                            71        40          5           5                                            72        40          5           5                                            73        40          5           5                                            74        40          5           5                                            75        40          5           5                                            76        40          5           5                                            77        40          5           5                                            78        40          5           5                                            79        40          5           5                                            80        40          5           5                                            81        40          5           5                                            82        40          5           5                                            83        40          5           5                                            84        40          5           5                                            85        40          5           5                                            86        40          5           5                                            87        40          5           5                                            88        40          5           5                                            89        40          5           5                                            90        40          5           5                                            91        40          5           5                                            92        40          5           5                                            93        40          5           5                                            94        40          5           5                                            95        40          5           5                                            96        40          5           5                                            97        40          5           5                                            98        40          5           5                                            99        40          5           5                                            100       40          5           5                                            101       40          5           5                                            102       40          5           5                                            103       40          5           5                                            104       40          5           5                                            105       40          5           5                                            106       40          5           5                                            107       40          5           5                                            108       40          5           5                                            109       40          5           5                                            110       40          5           5                                            111       40          5           5                                            112       40          5           5                                            113       40          5           5                                            114       40          5           5                                            115       40          5           5                                            116       40          5           5                                            117       40          5           5                                            118       40          5           5                                            119       40          5           5                                            120       40          5           5                                            121       40          5           5                                            122       40          5           5                                            123       40          5           5                                            124       40          5           5                                            125       40          5           5                                            126       40          5           5                                            127       40          5           5                                            128       40          5           5                                            129       40          5           5                                            130       40          5           5                                            131       40          5           5                                            132       40          5           5                                            133       40          5           5                                            134       40          5           5                                            ______________________________________                                    

TEXT EXAMPLE 3 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of Japanese millet, oat, radish and velvetleaf were sowed and cultivated for 10 days in a greenhouse. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 21.

                  TABLE 21                                                         ______________________________________                                                    Herbicidal activity                                                 Compound                                                                               Dosage   Japanese                                                      No.     (g/are)  millet   Oat   Radish                                                                               Velvetleaf                               ______________________________________                                          2      40       5        5     5     5                                         3      40       5        5     5     --                                       11      40       5        5     5     5                                        12      40       5        5     5     5                                        13      40       5        5     5     5                                        20      40       5        5     5     5                                        21      40       5        5     5     5                                        22      40       5        5     5     5                                        23      40       5        5     5     5                                        24      40       5        5     5     5                                        25      40       5        5     5     5                                        26      40       5        5     5     --                                       28      40       5        5     5     --                                       29      40       5        5     5     --                                       30      40       5        5     5     --                                       33      40       5        5     5     4                                        41      40       5        5     5     --                                       54      40       5        5     5     4                                        56      40       5        5     5     4                                        86      40       5        5     5     5                                        87      40       5        5     5     5                                        88      40       5        5     5     5                                        89      40       5        5     5     4                                        91      40       5        5     5     --                                       92      40       5        5     5     5                                        93      40       5        5     5     4                                        95      40       5        5     5     4                                        97      40       5        5     4     --                                       98      40       5        5     5     --                                       99      40       5        5     5     --                                       100     40       5        5     5     --                                       101     40       5        5     5     4                                        102     40       5        5     5     4                                        103     40       5        5     --    --                                       105     40       5        5     5     --                                       106     40       5        5     5     --                                       107     40       5        5     5     --                                       108     40       5        5     4     4                                        109     40       5        5     --    --                                       110     40       5        5     --    --                                       111     40       5        5     5     5                                        114     40       5        5     5     --                                       ______________________________________                                    

TEST EXAMPLE 4 Foliage treatment test in plow field

Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of radish and velvetleaf were sowed and cultivated for 10 days in a greenhouse. Thereafter, the precribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted wih a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a samll-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 22.

                  TABLE 22                                                         ______________________________________                                         Compound  Dosage       Herbicidal activity                                     No.       (g/are)      Radish  Velvetleaf                                      ______________________________________                                         11        20           5       5                                               12        20           5       5                                               13        20           5       5                                               20        20           5       5                                               21        20           5       5                                               22        20           5       5                                               23        20           5       5                                               24        20           5       5                                               25        20           5       5                                               B         20           0       0                                               ______________________________________                                    

TEST EXAMPLE 5 Treatment test under flooded condition in paddy field

Paddy-field soil was filled in a cylindrical plastic pot (diameter, 8 cm; depth, 12 cm), and the seeds of barnyardgrass were incorporated from 1 to 2 cm deep in the soil. After creating the state of paddy field by flooding, the test plants were cultivated in a greenhouse. After 6 days (initial stage of emergence of weeds), the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with 5 ml of water, and applied to the water surface. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 23.

                  TABLE 23                                                         ______________________________________                                         Compound     Dosage  Herbicidal activity                                       No.          (g/are) Barnyardgrass                                             ______________________________________                                          1           40      5                                                          2           40      5                                                          3           40      5                                                          4           40      5                                                          5           40      5                                                          6           40      5                                                          7           40      5                                                          8           40      5                                                          9           40      5                                                         10           40      5                                                         11           40      5                                                         12           40      5                                                         13           40      5                                                         14           40      5                                                         15           40      5                                                         16           40      5                                                         17           40      5                                                         18           40      5                                                         19           40      5                                                         20           40      5                                                         21           40      5                                                         22           40      5                                                         23           40      5                                                         24           40      5                                                         25           40      5                                                         26           40      5                                                         27           40      5                                                         28           40      5                                                         29           40      5                                                         30           40      5                                                         31           40      5                                                         32           40      5                                                         33           40      5                                                         34           40      5                                                         35           40      5                                                         36           40      5                                                         37           40      5                                                         38           40      5                                                         39           40      5                                                         40           40      5                                                         41           40      5                                                         42           40      5                                                         43           40      5                                                         44           40      5                                                         45           40      5                                                         46           40      5                                                         47           40      5                                                         48           40      5                                                         49           40      5                                                         50           40      5                                                         51           40      5                                                         52           40      5                                                         53           40      5                                                         54           40      5                                                         55           40      5                                                         56           40      5                                                         57           40      5                                                         58           40      5                                                         59           40      5                                                         60           40      5                                                         61           40      5                                                         62           40      5                                                         64           40      5                                                         65           40      5                                                         66           40      5                                                         67           40      5                                                         68           40      5                                                         69           40      5                                                         70           40      5                                                         71           40      5                                                         72           40      5                                                         73           40      5                                                         74           40      5                                                         75           40      5                                                         76           40      5                                                         77           40      5                                                         78           40      5                                                         79           40      5                                                         80           40      5                                                         81           40      5                                                         82           40      5                                                         83           40      5                                                         84           40      5                                                         85           40      5                                                         86           40      5                                                         87           40      5                                                         88           40      5                                                         89           40      5                                                         90           40      5                                                         91           40      5                                                         92           40      5                                                         93           40      5                                                         94           40      5                                                         95           40      5                                                         96           40      5                                                         97           40      5                                                         98           40      5                                                         99           40      5                                                         100          40      5                                                         101          40      5                                                         102          40      5                                                         103          40      5                                                         104          40      5                                                         105          40      5                                                         106          40      5                                                         107          40      5                                                         108          40      5                                                         109          40      5                                                         110          40      5                                                         111          40      5                                                         112          40      5                                                         113          40      5                                                         114          40      5                                                         115          40      5                                                         116          40      5                                                         117          40      5                                                         118          40      5                                                         119          40      5                                                         120          40      5                                                         121          40      5                                                         122          40      5                                                         123          40      5                                                         124          40      5                                                         125          40      5                                                         126          40      5                                                         127          40      5                                                         128          40      5                                                         129          40      5                                                         130          40      5                                                         131          40      5                                                         132          40      5                                                         133          40      5                                                         134          40      5                                                         ______________________________________                                    

TEST EXAMPLE 6 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, johnsongrass and green foxtail were sowed and covered from 1 to 2 cm deep with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The result are shown in Table 24.

                                      TABLE 24                                     __________________________________________________________________________     Compound                                                                             Dosage                                                                             Herbicidal activity                                                  No.   (g/are)                                                                            Soybean                                                                             Cotton                                                                             Barnyardgrass                                                                          Johnsongrass                                                                          Green foxtail                                __________________________________________________________________________      2    2.5 0    0   5       5      5                                                  0.63                                                                               0    0   4       --     4                                            32    2.5 0    0   5       4      5                                                  0.63                                                                               0    0   --      3      5                                            33    2.5 0    0   5       5      5                                            41    2.5 0    0   5       4      5                                                  0.63                                                                               0    0   4       --     5                                            59    2.5 0    0   5       4      5                                            70    2.5 0    0   5       5      5                                                  0.63                                                                               0    0   3       --     --                                           74    2.5 0    0   5       5      5                                                  0.63                                                                               0    0   3       3      --                                           77    2.5 0    0   5       4      4                                            98    2.5 0    0   5       5      5                                                  0.63                                                                               0    0   5       4      5                                            99    2.5 0    0   5       4      5                                                  0.63                                                                               0    0   4       --     4                                            100   2.5 0    0   4       4      5                                                  0.63                                                                               0    0   --      3      3                                            A     2.5 0    0   0       1      0                                                  0.63                                                                               0    0   0       0      0                                            B     2.5 0    0   2       1      2                                                  0.63                                                                               0    0   0       0      0                                            __________________________________________________________________________

TEST EXAMPLE 7 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat and fall panicum wwere sowed and covered from 1 to 2 cm deep with soil. The prescribed amount of the emulsifiable concentrates the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 25.

                                      TABLE 25                                     __________________________________________________________________________     Compound                                                                             Dosage                                                                             Herbicidal activity                                                  No.   (g/are)                                                                            Corn                                                                              Barnyardgrass                                                                          Large crabgrass                                                                        Johnsongrass                                                                          Green foxtail                                                                         Oat                                                                               Fall panicum                     __________________________________________________________________________     2     2.5 0  5       5       4      5      4  5                                26    2.5 0  5       5       5      5      -- --                               70    2.5 0  5       4       5      5      5  5                                A     2.5 0  0       1       1      0      0  1                                C     2.5 0  3       1       1      1      0  5                                __________________________________________________________________________

TEST EXAMPLE 8 Soil treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of wheat, barley, wild oat, blackgrass and annual bluegrass were sowed and covered from 1 to 2 cm deep with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 30 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 26.

                  TABLE 26                                                         ______________________________________                                                   Herbicidal activity                                                  Compound                                                                               Dosage                Wild  Black-                                                                               Annual                               No.     (g/are) Wheat   Barley                                                                               oat   grass bluegrass                            ______________________________________                                         2       2.5     --      0     5     5     5                                             0.63   1       0     4     5     5                                    26      2.5     0       0     --    5     4                                    70      2.5     1       0     4     4     5                                    B       2.5     1       0     0     2     0                                             0.63   0       0     0     0     0                                    ______________________________________                                    

TEST EXAMPLE 9 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat and annual bluegrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 5 liter/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 27. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 27                                     __________________________________________________________________________                 Herbicidal activity                                                Compound                                                                              Dosage                                                                  No.    (g/are)                                                                             Soybean                                                                             Cotton                                                                             Barnyardgrass                                                                          Large crabgrass                                                                        Johnsongrass                                                                          Green foxtail                                                                         Oat                                                                               Annual                   __________________________________________________________________________                                                           bluegrass                32     2.5  0    0   5       5       5      5      5  3                               0.63 0    0   4       4       5      4      4  --                       41     2.5  0    0   5       5       5      5      5  4                               0.63 0    0   5       4       4      4      5  3                        51     2.5  0    0   5       5       5      5      5  3                               0.63 0    0   5       4       --     5      4  --                       54     2.5  0    0   5       5       5      5      5  --                              0.63 0    0   5       4       5      5      5  --                       59     2.5  0    0   5       5       5      5      5  --                              0.63 0    0   5       5       5      4      4  --                       70     2.5  0    0   5       5       5      5      5  3                               0.63 0    0   5       4       4      3      4  --                       74     2.5  0    0   5       5       5      5      4  4                               0.63 0    0   5       4       5      4      4  3                        75     2.5  0    0   5       5       5      5      4  4                               0.63 0    0   5       4       5      3      4  3                        79     2.5  0    0   5       4       4      3      5  --                              0.63 0    0   5       --      3      --     4  --                       A      2.5  0    0   3       1       2      3      3  2                               0.63 0    0   1       0       0      1      0  0                        B      2.5  0    0   3       1       2      3      3  3                               0.63 0    0   2       0       0      2      0  0                        __________________________________________________________________________

TEST EXAMPLE 10 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of soybeam cotton, large crabgrass, johnsongrass, green foxtail, oat and annual bluegrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage, and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 28. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 28                                     __________________________________________________________________________                       Herbicidal activity                                          Compound No.                                                                            Dosage (g/are)                                                                          Soybean                                                                             Cotton                                                                              Large crabgrass                                                                        Johnsongrass                                                                          Green foxtail                                                                         Oat Annual                   __________________________________________________________________________                                                           bluegrass                33       2.5      0    0    5       5      5      5   4                                 0.63     0    0    5       5      5      5   4                        56       2.5      0    0    5       4      5      5   3                                 0.63     0    0    --      4      4      5   --                       C        2.5      0    0    4       3      4      4   0                                 0.63     0    0    3       1      3      3   0                        __________________________________________________________________________

TEST EXAMPLE 11 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat, annual bluegrass and blackgrass were sowed and cultivated for 18 days. Thererafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 5 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 29. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 29                                     __________________________________________________________________________                 Herbicidal activity                                                Compound                                                                              Dosage                                       Annual                     No.    (g/are)                                                                             Soybean                                                                             Cotton                                                                             Barnyardgrass                                                                          Crabgrass                                                                            Johnsongrass                                                                          Green foxtail                                                                         Oat                                                                               bluegrass                                                                           Blackgrass            __________________________________________________________________________     89     2.5  0    0   5       5     5      5      5  4    5                            0.63 0    0   5       4     4      4      5  --   4                     91     2.5  0    0   5       5     5      5      5  4    5                            0.63 0    0   5       5     4      5      4  --   --                    92     2.5  0    0   5       5     5      5      5  4    5                            0.63 0    0   5       4     5      5      4  --   4                     93     2.5  0    0   5       5     5      5      5  4    5                            0.63 0    0   5       5     5      4      5  4    4                     97     2.5  0    0   5       5     5      5      5  --   5                            0.63 0    0   5       4     4      5      4  --   4                     98     2.5  0    0   5       5     5      5      5  --   5                            0.63 0    0   5       4     5      5      5  --   4                     A      2.5  0    0   3       1     2      3      3  2    2                            0.63 0    0   1       0     0      1      0  0    0                     B      2.5  0    0   3       1     2      3      3  3    3                            0.63 0    0   2       0     0      2      0  0    0                     D      2.5  --   --  1       0     0      0      0  0    0                            0.63 --   --  0       0     0      0      0  0    0                     __________________________________________________________________________

TEST EXAMPLE 12 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area. 33×23 cm² ; depth, 121 cm), and the seeds of cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat, annual bluegrass and blackgrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 7 to 15 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 30. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 30                                     __________________________________________________________________________               Herbicidal activity                                                  Compound                                                                             Dosage                                                                   No.   (g/are)                                                                            Cotton                                                                             Barnyardgrass                                                                          Large crabgrass                                                                        Johnsongrass                                                                          Green foxtail                                                                         Oat                                                                               Annual bluegrass                                                                        Blackgrass             __________________________________________________________________________     2     2.5 0   5       5       5      5      5  4        5                            0.63                                                                               0   5       4       5      5      5  --       4                      A     2.5 0   3       1       2      3      3  2        2                            0.63                                                                               0   1       0       0      1      0  0        0                      B     2.5 0   3       1       2      3      3  3        3                            0.63                                                                               0   2       0       0      2      0  0        0                      D     2.5 --  1       0       0      0      0  0        0                            0.63                                                                               --  0       0       0      0      0  0        0                      __________________________________________________________________________

TEST EXAMPLE 13 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass, green foxtail and oat were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foilage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 2-leaf stage and from 7 to 15 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 31. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 31                                     __________________________________________________________________________                     Herbicidal activity                                            Compound No.                                                                           Dosage (g/are)                                                                         Corn                                                                              Barnyardgrass                                                                          Large crabgrass                                                                        Johnsongrass                                                                          Green foxtail                                                                         Oat                           __________________________________________________________________________      2      0.63    1  5       4       5     5       4                                     0.16    0  4       --      4     4       4                              3      0.63    0  5       4       3     4       3                             26      0.63    1  5       4       3     5       4                             70      0.63    1  5       3       4     5       4                             79      0.63    0  5       4       4     4       4                             C       0.63    3  5       2       1     4       3                                     0.16    1  4       0       1     3       0                             __________________________________________________________________________

TEST EXAMPLE 14 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 15×10 cm² ; depth, 7 cm), and the seeds of corn, barnyardgrass, large crabgrass, and green foxtail were sowed and cultivated for 14 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 6 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state opf growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 4-leaf stage and from 2 to 42 cm in height. Fifteen days after treatment, the herbicidal activity was examined. The results are shown in Table 32. These tests were carried out in a greenhouse throught the entire period of test.

                  TABLE 32                                                         ______________________________________                                                   Herbicidal activity                                                  Compound                                                                               Dosage                    Large  Green                                 No.     (g/are) Corn    Barnyardgrass                                                                            crabgrass                                                                             foxtail                               ______________________________________                                         2       0.75    0       5         5      5                                     70      0.75    0       5         4      5                                     A       0.75    1       1         0      0                                     C       0.75    2       5         3      4                                     ______________________________________                                    

TEST EXAMPLE 15 Foliage treatment test in plow field

Plow-field soil was filled in a vat (area, 33×23 cm² ; depth, 11 cm), and the seeds of tall morningglory, common cocklebur, velvetleaf, common chickweed, black nightshade and redroot pigweed were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 2-leaf stage and from 3 to 10 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 33. These tests were carried out in a greenhouse through the entire period of test.

                                      TABLE 33                                     __________________________________________________________________________               Herbicidal activity                                                  Compound                                                                             Dosage                                                                             Tall   Common      Common                                                                               Black Redroot                               No.   (g/are)                                                                            morningglory                                                                          cocklebur                                                                            Velvetleaf                                                                           chickweed                                                                            nightshade                                                                           pigweed                               __________________________________________________________________________     2     10  5      4     4     5     4     4                                     B     10  0      0     0     0     0     0                                     __________________________________________________________________________

TEST EXAMPLE 16 Treatment test under flooded condition in paddy field

Paddy-field soil was filled in 1/5000 area Wagner's pots, and the seeds of barnyardgrass were incorporated from 1 to 2 cm deep in the soil. After creating the state of paddy field by flooding, rice plants in a 3-leaf stage were transplanted and cultivated in a greenhouse. After 4 days, the presecribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with 10 ml of water and applied to the water surface, and the depth of water was made 4 cm. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity and phytotoxicity. The results are shown in Table 34. In this test, water leakage corresponding to a water level of 3 cm/day was carried out for 2 days from the day subsequent to the treatment.

                  TABLE 34                                                         ______________________________________                                         Compound  Dosage      Herbicidal activity                                      No.       (g/are)     Rice   Barnyardgrass                                     ______________________________________                                          2        1.25        0      5                                                           0.32        0      4                                                 10        1.25        0      5                                                           0.32        0      4                                                 28        1.25        1      5                                                           0.32        0      4                                                 29        1.25        0      5                                                           0.32        0      4                                                 30        1.25        0      5                                                           0.32        0      5                                                 51        1.25        1      5                                                           0.32        0      4                                                 70        1.25        1      5                                                           0.32        0      5                                                 74        1.25        1      5                                                           0.32        0      5                                                 87        1.25        0      5                                                           0.32        0      5                                                 98        1.25        0      5                                                           0.32        0      5                                                 99        1.25        0      5                                                           0.32        0      5                                                 100       1.25        0      5                                                           0.32        0      5                                                 E         1.25        1      2                                                           0.32        0      0                                                 ______________________________________                                    

TEST EXAMPLE 17 Foliage treatment test in plow field

Plow-field soil was filled in a concrete-pot (area, 40×35 cm² ; depth, 35 cm), and the seeds of wheat, annual bluegrass, wild oat and blackgrass were sowed and cultivated for 41 days. Thereafer, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 7 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that the time varied with the kind thereof, but they were in a 2 to 3-leaf stage. Twenty-one days after treatment, the herbicidal activity was examined. The results are shown in Table 35. These tests were carried out in outdoors through the entire period of test.

                  TABLE 35                                                         ______________________________________                                                    Herbicidal activity                                                 Compound                                                                               Dosage            Annual Wild                                          No.     (g/are)  Wheat    bluegrass                                                                             oat   Blackgrass                              ______________________________________                                         2       0.3      0        4      4     4                                       F       0.3      0        0      1     1                                       ______________________________________                                    

TEST EXAMPLE 18 Foliage treatment test in plow field

In plow-field wherein ridging was carried out so that the upper row space was 1 meter was sowed the seeds of corn, johnsongrass, green foxtail, large crabgrass and barnyardgrass. When the corn grew to a 4-leaf stage and the weeds grew to a 2 to 4-leaf stage, the rows were partitioned into test plots of 3 m² in area. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 3 liters/are and foliage-applied to the whole surface of the test plots by means of a small-sized sprayer (three replications). After 30 days, the herbicidal activity was examined. The results are shown in Table 36.

                  TABLE 36                                                         ______________________________________                                         Com-          Herbicidal activity                                              pound Dosage         Johnson-                                                                              Green Large  Barnyard-                             No.   (g/are) Corn   grass  foxtail                                                                              crabgrass                                                                             grass                                 ______________________________________                                         2     1       0      4      5     5      5                                     D     20      0      0      4     4      3                                     ______________________________________                                     

What is claimed is:
 1. A compound of the formula, ##STR154## wherein R¹ is methyl, ethyl or propyl; R³ is hydrogen or methyl; R⁴ is hydrogen or methyl; R⁵ is hydrogen or methyl group, and when R⁵ is a hydrogen atom, R⁶ is a hydrogen atom or a alkoxycarbonyl group, and when R⁵ is a methyl group, R⁶ is hydrogen; X is CH or nitrogen; Y is hydrogen or halogen; Z is trifluoromethyl, trifluoromethyloxy or 1,1,2,2-tetrafluoroethyoxy; and n is an integer of
 0. 2. The compound according to claim 1, of the formula, ##STR155## wherein X is a CH group or a nitrogen atom and R¹ is a methyl, ethyl or propyl group. 